Gilman Reagent & Organocuprates

This organic chemistry video tutorial provides a basic introduction into the Gilman reagent also known as an organocuprate. It discusses how to synthesize the organocuprate from an organolithium reagent. It also discusses the reaction between alkyl halides and unsaturated ketones with the gilman reagent.
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[@1495978707]

Thanks for the example at the end, that was really helpful for understanding the point of Gilman

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[@nandukrishna8142]

Bro this is underrated video, its an AIEEE 2005 question :)

[@badhombres1190]

Is this topic (the gilman reagent) a very popular question on the PCAT?

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[@nevermind4329]

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[@jasmine9581]

Haha Gilman reagent the same week we mention them
First exam next Tuesday 👌🏾

[@misozichimenya5050]

Thanks

[@nicowhitlock2855]

How is it that Gilman reagents can replace halides on sp2 hybrodized carbons (seeing as that can't happen w/ the SN2 mechanism). Is this mech not SN2?

[@WiShInGdRaGoN1324]

Gilman reagents can undergo both addition and nucleophilic reactions. In the case of alpha, beta unsaturated ketones, it's (conjugate) addition. For alkyl halides, it's a carbon-carbon-making SN2 reaction

[@reynavalo6201]

Underrated

[@ev446]

Sick!! But wheres the mechanism dawg? Is this a metal mediated thing? Association? Reductive elimination?? Whats going on my dude?

[@parthmadaan3399]

But sir grignard also do 1-4 addition

[@fridazayouna6926]

What’s a veno or aero halide

[@sijmenkroon5972]

isnt a big part of gilman reagents that they can replace the Cl of a acid chloride

[@WiShInGdRaGoN1324]

Yes, into a ketone, and it reacts no further.

[@-taeri4020]

show the curly arrows please

[@hassanalmutari6524]

please make more biology videos thanks