Zinc makes The Dip safer. I think.

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  • čas přidán 29. 01. 2022
  • The Dip is a lead removal method that uses equal parts Vinegar and Hydrogen Peroxide. It is very effective but leaves behind nasty Lead Acetate. We can use Zinc metal to turn that lead acetate into lead metal again.
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Komentáře • 324

  • @JohnnysReloadingBench
    @JohnnysReloadingBench  Před 2 lety +2

    Check out this follow up video from The VSO Gun Channel. He knows a lot more about chemistry and gives an easier solution. czcams.com/video/MaOBNJvRx0o/video.html

  • @the1andonlySherlock
    @the1andonlySherlock Před 2 lety +107

    Hey Johnny, if you want to speed up the reaction you can use zinc powder instead of a large piece of zinc. The increased surface area of the powder will help a lot.

    • @StonyRC
      @StonyRC Před 2 lety

      Ooh, good idea!

    • @JohnnysReloadingBench
      @JohnnysReloadingBench  Před 2 lety +11

      Nilered did that in the 2nd video, so I considered it. I was holding out hope that maybe we could grow some cool looking crystals, and we did a little bit. Like you say, I'm sure all that surface area would help a lot.

    • @jackshett
      @jackshett Před 2 lety +4

      Maybe for something reusable you could get thin sheets, maybe foil, and coil it up to get surface area too.

    • @scrooge8117
      @scrooge8117 Před 2 lety

      @@JohnnysReloadingBench Try leaving it overnight in Coke once in a while

  • @JohnnysReloadingBench
    @JohnnysReloadingBench  Před 2 lety +40

    This seems like the sort of video I will soon delete in shame.
    Also: I bought a Creality Ender 3 S1. We can talk about it on the stream tomorrow night, but it will be a few weeks before I get a video put together. It's still in the box because I've been staring at lead all week.

    • @mckimmym
      @mckimmym Před 2 lety +3

      No worries, interesting stuff. Need to see if you can cast a bullet from what you collect :). I’ve got a supressor on order so this will be in the back of my mind for future consideration. Maybe some stronger acids could move the process along faster?

    • @joearledge1
      @joearledge1 Před 2 lety +12

      I vote for leaving the video up, I don't see any problem with it. Also, I may be wrong, but I think the white precipitate may have been lead that fell out of solution because you're solution reached its saturation point. Keep up the good work Sir.

    • @tacticalrabbit308
      @tacticalrabbit308 Před 2 lety +6

      Don't delete the video please I may want to watch it again

    • @joearledge1
      @joearledge1 Před 2 lety

      FYI kinda related to this but more relevant to your annealing, "reese on the range" is a metallurgist on yt and he has a very good explanation of the science of annealing on his channel. Thought you may be able to consult him on other metallurgy questions too and it looks like he watches your channel as well. Just thought I'd let you know Sir.

    • @chrisroberts3963
      @chrisroberts3963 Před 2 lety

      Because of you I bought an Ender 5 Pro and the Lee APP. I got a couple 3D projects in mind. And I just can’t get over the speed of the Lee once you got it set up.
      Quick question - what size tubes do you buy that fits the collator?

  • @ecliptix1
    @ecliptix1 Před 2 lety +47

    Fellow student of CZcams Chemistry University here, I think what happened is due to what's called the "Reactivity Series of Metals", basically some metals are more reactive, and others less so. You can use this to swap one metal for another in a solution, and since Iron (in the brush handle & bristles) is more reactive than Lead, it was not only dissolving due to the solution, but whatever lead had dissolved into the solution was immedately being replaced by iron from the handle. Zinc is more reactive than iron, so when you put the zinc coil in that nasty solution, both the iron and the lead were precipitating out which is why you got a different looking precpitate.
    This is used in Gold refnining because Gold is the least reactive metal. A process called "inquartation" can be used whereby carat gold (i.e., gold that is not pure) is alloyed with sterling silver to make it easier to dissolve out the silver and base metals. The pure metallic gold is left behind, and then the solution that is full of silver, copper, etc can be refined using the reactivity series to remove just the silver by putting in pieces of copper.

    • @colsoncustoms8994
      @colsoncustoms8994 Před 2 lety

      Alright he summed up my comment way better than I wrote it haha. Any experience with iron sulfate to precipitate gold in solution? I think I accidentally screwed up with adding more hydrochloric acid and peroxide over and over and eventually got the gold in solution (over a week or 2, no heat). Can’t find any sodium metabisulfate locally but did locate copperas (iron sulfate).

  • @loganwebb6447
    @loganwebb6447 Před 2 lety +1

    I watch a lot of CZcams and and I always enjoy logging in to see a post from “Johnny”. Keep up the good work and don’t leave CZcams. We love watching this stuff even if it isn’t what we do in our free time. This was an interesting video for me because of my chem background in college recently.

  • @nate998877
    @nate998877 Před 2 lety +9

    I'm not a gun guy at all. I don't know how common any of this is, but I think it's really cool that you've potentially made this process safer. Bioavailable lead being dumped into the environment is serious & if more people start doing this that's awesome. Also really fun chemistry.

  • @VSO_Gun_Channel
    @VSO_Gun_Channel Před 2 lety +37

    This was cool. I might duplicate from the perspective of a classically trained chemist.
    Also, that copper solution at the end is either copper acetate or copper hydroxide. Maybe both. I’m guessing acetate because of the excess vinegar in the original peracetic acid mix. To test this take a small sample (maybe 100ml or so) and get some clear, strong liquor like everclear or 151 and dilute it. If precipitates you have copper acetate. If it doesn’t then you have the hydroxide.
    This will determine how you go about cleaning up the copper

    • @JohnnysReloadingBench
      @JohnnysReloadingBench  Před 2 lety +13

      That would be really awesome. Correct it, refine it, explain it, expand it, refute it...I'd be happy to hear anything from someone that understands what's going on.

    • @notamouse5630
      @notamouse5630 Před 2 lety +2

      Easier: freeze distill metal acetates, the 90% of the acetates will form a crust on the surface and also suspend as particles, I just did this for copper acetate. Then filter for pure metal acetates.

    • @VSO_Gun_Channel
      @VSO_Gun_Channel Před 2 lety +8

      @@notamouse5630 I hate freeze distillation, makes a mess. I’m a classical wet chemist- contain everything in a liquid system and kick species out chemically.

    • @notamouse5630
      @notamouse5630 Před 2 lety +2

      @@VSO_Gun_Channel Depends upon whether the container is glass, Also there is the option of freeze distillation, scraping the crust, crushing and centrifuging the slush, and taking the concentrate for round 2 of freeze distillation. All without glassware, which was my reason. I am a classic kitchen chemist reusing polymer ice cream cointainers. This freeze distillation makes both a crystalline product and a concentrate.

    • @paintballplayer700
      @paintballplayer700 Před 2 lety +1

      @@JohnnysReloadingBench Aluminum powder is relatively cheap (Alpha Chemical sells 2lb for $26) and IIRC is a stronger reducing agent than Zinc, plus the powder will react faster. Would recommend trying it.

  • @rmbettac
    @rmbettac Před 2 lety

    Fascinating results. Thanks for the thorough documentation, as always.

  • @TheMerlinmk19
    @TheMerlinmk19 Před 2 lety +11

    There is a bunch that i never knew...particularly the lead acetate hazard - Thanks! I've been looking at a couple of suppressors that state they are "maintenance free" but looking at what you got out of yours makes me second guess those claims.

    • @yourfavoritelawnguy2722
      @yourfavoritelawnguy2722 Před 2 lety

      theres no such thing really. All will need to be either cleaned or re-cored eventually

  • @stacybrown3714
    @stacybrown3714 Před 2 lety +1

    Wow this is interesting. I sent my SpecWar back to silencerco a couple of years ago. It sucks waiting for it to come back but they did a great job and updated the locking ring thingy at no charge. Still your chemistry is awesome. Thanks for another great video.

  • @randomchaos606
    @randomchaos606 Před 2 lety

    This is why I love your channel, never gong to know what I'm go get but it's always entertaining.

  • @StonyRC
    @StonyRC Před 2 lety +1

    Seriously interesting experiments Sir - and don't be discouraged if things go awry. That's what experimentation is all about. I laughed heartily at your term "Chinesium" ... that's a new element that I'll be quoting often!

    • @dubful1
      @dubful1 Před 2 lety

      I laughed at “Chinesium” too and think I’ll use that adjective for now on. Lol

  • @astacrouse
    @astacrouse Před 2 lety +6

    "You're a frickin hill-jack, trying to do something with chemistry..."! Love it! Chemistry for the common man! Definitely interesting and equally entertaining. Do it again

  • @777rev
    @777rev Před 2 lety

    NileRed enjoyed here!! Great vid bossman! Also very very nice and interesting use of chemistry to do what clean a suppressor

  • @ricksters11
    @ricksters11 Před 2 lety

    You discover things similarly to the ways I do, hopefully we don't die! Very enjoyable to watch someone else do it. Thanks!

  • @Metalhammer1993
    @Metalhammer1993 Před 2 lety +6

    As a chemist I love that experiment! That's why we do research so it can be tested for actual usecases! Nice job! (And don't worry it failed. This is what engineers do. They test what should work as a usecase and then often spend years ironing the kinks out)

  • @robertbrewer2055
    @robertbrewer2055 Před 2 lety

    Not a video that I would normally watch, but you are just so dang entertaining and I appreciate your willingness to "experiment" for our benefit. When will you start suppressor cleaning business?

  • @gunnyp8272
    @gunnyp8272 Před rokem

    "This is where everything goes wrong"!!!
    I giggled like a school girl when you said that and that is exactly why I love this channel.

  • @johnstevenson9818
    @johnstevenson9818 Před 2 lety

    I appreciate the your info even and especially if you feel like a "noob". There are so many things in life that would be so much safer and easier just because others share their experience. Thank you.

  • @evilgibson
    @evilgibson Před 2 lety +6

    I think that line might be the separation line of zinc acetate and lead acetate since they have different weights. Lead has more molecular weight so it would gravitate below the zinc acetate.
    That could explain why the reaction slowed way down once that line went below the zinc - it's harder for the lead acetate to get close to zinc metal since it is surrounded by zinc acetate.
    Suggesting a stir bar to keep the solution made of the acetates mixed or keep the zinc metal close to the bottom.

  • @erice_twentyone13
    @erice_twentyone13 Před 2 lety

    Outstanding video!! Always well presented information.

  • @boz7338
    @boz7338 Před 2 lety +6

    Dude, seriously impressed with your experiment. Would like to see more like that concerning firearms. Where would you dispose of the liquid in the container or who would you call to find out?
    Thank you for the information 🔫👍🏻

  • @DaveL9170
    @DaveL9170 Před 2 lety +1

    That Hybrid.46 looks like it’s seen better days. I’ve had one for years and have never even once cleaned mine. In fact, the directions say do not clean! I should a few rounds of super high power .375 rounds through mine to blow out stuff.

  • @jeremymcauliff8485
    @jeremymcauliff8485 Před 2 lety +3

    I've had great success with DUB Aluminum wheel cleaner. I have a Griffin Armament Sportsman that is all aluminum. It gained some weight and the DUB cleaner did a great job loosening and dissolving the crud. It didn't harm the finish or base metal either.
    I have used "the dip" before with Rimfire cans. You can increase it's aggressiveness by using it in an ultrasonic cleaner. I don't use it in the ultrasonic tank. I put my baffles (Stainless only) in a spaghetti sauce jar. Add dip solution until the baffles are covered then place the jar in the ultrasonic tank. Add plain water to the tank and run as you normally would.
    The dip solution can be neutralized with table salt when you are finished with it. Or save the solution and drop off at your local Hazmat days.

    • @Matt-dc8lp
      @Matt-dc8lp Před 2 lety +1

      Don't know about Dub but be very careful with aluminum wheel cleaners in general. Several of them contain hydrofluoric acid which is super nasty stuff. It burns your skin like other acids except that it penetrates the skin surface and doesn't wash off with water.

  • @bobvagene
    @bobvagene Před 2 lety +1

    I did the dip on some individual baffles of my first 9mm can that I had been running 22 through. I knew the hazards. While it was the most effective and efficient way to deal with lead build up, I decided not to do it again. Now I just scrape off lead by hand with a pick maybe once a year. Sealed cans I don't even mess with.

  • @colsoncustoms8994
    @colsoncustoms8994 Před 2 lety +9

    Alright the blue color of the last dip is copper. Once the copper goes in solution it will cement out on iron (why it plated on the can). The iron replaced it the exact same way the zinc does the lead. So to get it out of solution you can literally throw any scrap iron in and it’ll drop out. I’d avoid stainless as it will add other stuff like chromium, vanadium, etc. which may be more toxic than the copper. Plain old low grade steel is your best bet. You can also use electrolysis (which would put you on the road to plating lead projectiles for instance..). I know sodium metabisulfate and iron sulfate are 2 used to drop gold and other precious metals, not sure if they’d do copper but might be worth looking into. Oh and diluting the solution with water will make the lead and silver oxide drop out of solution.

  • @BoltActionReloading
    @BoltActionReloading Před 2 lety +16

    I had no idea about any of this kind of thing. Seems if it weren't so hard to send suppressors everywhere you could have a reasonably priced cleaning service just so you didn't have to deal with that kind of crap.

    • @DanielBoone337
      @DanielBoone337 Před 2 lety +1

      My thoughts exactly...

    • @tyler6147
      @tyler6147 Před 2 lety

      If you have a suppressor with some build up in it just get some Boretech C4. Just plug the bore with a silicone plug and fill it up. It gave me excellent results. Now Boretech has a suppressor specific cleaning kit as well.

    • @Lethal_Intent
      @Lethal_Intent Před 2 lety

      I'm glad all my moderators are strippable so i don't have to deal with this all i have to do is open it up, use something to clean like boretech eliminator and brush away.

  • @jamespugh
    @jamespugh Před 2 lety

    Jrb thanks for doing this . Keep this video up it's a learning tool .

  • @stevenmarcus2709
    @stevenmarcus2709 Před 2 lety +3

    I soak my suppressors in BoreTech Eliminator every one thousand or so rounds. It keeps them maintained and I don’t gain any weight. I soak for one hour, rinse with water then rinse withBallistol and water mix of 90 percent water and ten percent Ballistol. I have never had any issue whatsoever but.. my finish is long gone, it’s been cooked, painted over and re painted over five times.

  • @Allanhorns
    @Allanhorns Před 2 lety

    Like gold refining, you want to precipitate the lead out. Once done you can smelt it down and reconstitute into lead ingot. Low temps melt lead, so no need for toxic fumes. Once the lead is precipitate out you can reused your solution at least three times. It will be weaker, but it will still work. Once that last batch is done, add a base to neutralize and then disposed of safely.

  • @Rorschach1024
    @Rorschach1024 Před 2 lety +4

    A way to prevent hot spots in your UT cleaner is to put the suppressor in the cleaner in a jar, and put the jar in the tank and fill the space around the jar with water.

  • @funigui
    @funigui Před 2 lety

    This was super informative man. Its really interesting

  • @evanhart5537
    @evanhart5537 Před 2 lety

    I actually used CLR last week. Cleaned my Omega, but it took forever. But it is clean now. Also F-Class shooters are using CLR for cleaning carbon fouling in Stainless barrels.

  • @glen4130
    @glen4130 Před 2 lety

    I clicked to see reloading and got a chemistry lesson, still love the channel.

  • @texpatriot8462
    @texpatriot8462 Před 2 lety +14

    In Texas, my town has hazmat collection days from time to time. I can drive up to a parking lot and the state will dispose of hazardous chemicals for me (residential quantities only). I have never tried to do lead acetate, but it might be worth a few calls to Tennessee officials.

    • @homersaypian3798
      @homersaypian3798 Před 2 lety

      Howdy Tex! I’m also in Texas (North Central). Can you tell me what town or towns do this. I have a few jars that need to go away. Thanks!

    • @geologik7500
      @geologik7500 Před 2 lety

      @@homersaypian3798 almost every large-ish municipality will have a residential hazardous waste disposal site. I would try looking for your town + residential hazardous waste disposal.
      Sometimes it's a city-run location and sometime the local fire department will handle it.

    • @texpatriot8462
      @texpatriot8462 Před 2 lety

      @@homersaypian3798 you probably have to call your city or county. I don’t think residents of other towns can show up.

  • @bencase5120
    @bencase5120 Před 2 lety

    Hey Johnny, not sure if anyone has said it but I believe if you used a "bubbler" not sure the scientific name but the stopper on alcohol fermenting containers. This way only thing venting off would be the hydrogen and you wouldn't have to worry as much of spillover since the hole would be smaller. Great video. Hopefully going to start reloading after I buy my house and get out of my appartment

  • @deadfishporter
    @deadfishporter Před 2 lety

    I'll be coming back to this video in a week. I'm a big fan of chemistry and I want to see what where this goes. 👍

  • @adg1017
    @adg1017 Před 2 lety

    Super interesting. I don’t have a suppressor… yet. But I’m moving to Kentucky next month (from CA), so I’ll need this video at some point. Ha!

  • @ogchaxzor3562
    @ogchaxzor3562 Před 2 lety

    I am not a chemist but I did work at TBAC for some time. The suppressors they make are 100% titanium so I only recommend this with titanium suppressors only. CLR works really well at cleaning gunk out of suppressors. At TBAC they use the Zep brand CLR. It works really well getting the gunk out of them. If it is really bad you may need to repeat the process.

  • @colsoncustoms8994
    @colsoncustoms8994 Před 2 lety +1

    Lead oxide and silver oxide are water insoluble and form a white precipitate. I believe the lead will be destroyed/ converted if you boil it, which is how you separate the 2 if you’re trying to rev over the silver for instance. No idea how tin and antimony react with h2o2 and/or acidic acid.

  • @andrewmattiewalter
    @andrewmattiewalter Před 2 lety

    I think a large part of the solution change in color was due to the other elements that would be found along with lead I.e. Copper, powder and lead as well, compared to your first test with pure round ball lead. So the addition of these elements most likely negated some of the effectiveness of the solution.

  • @tommysaulter9171
    @tommysaulter9171 Před 2 lety +1

    I clean my guns and suppressors with a product named “Shooter’s Lube -Stage 1 Military Grade” weapon cleaner. I spray removable baffles, wait a few minutes, then simply wipe down with a cloth. Baffles look like brand new when done. Same for their tube. For non-removable baffles, just pour an ounce into tube, put a finger over inlet & outlet, and shake it up to completely cover/soak the innards. Then drain after a few minutes (I reclaim the contents for future use), then stand it up on its end where it will “self dry” in an hour or two...

  • @ron4hunting
    @ron4hunting Před 2 lety

    the piston clean is great for removing carbon on brakes and the bore . lots of f class guys use it or even clr . only it will remove bluing . it will even get a carboned up adjustable gas block lose .

  • @zerumsum1640
    @zerumsum1640 Před 2 lety +1

    Ok with my limited chemistry knowledge i will offer a few suggestions here:
    1: your bucket idea is ok for a waste bucket, but not the reaction vessel. The zinc will 'eat up' all the solution alongside the lead, unless the reaction turning the lead acetate to zinc in that solution requires lead acetate to be formed first.
    2: as a few others have noted, if you want to speed this up buy a bag of powdered zinc from the internet/a metal or chemistry supplier. wire's alright for surface area, but you want surface area here. basically goes (from most to least) powder, granules, pellets (shot), and then just chunks of it. i'd put wire around the shot level. if you could find zinc mesh that would work faster too, but may fill up with lead pretty quick as well. long story short the finer the better.
    also, if you can, take the suppressor apart first. again, surface area. with it all put together the reaction is limited by how fast the reactants (peroxide and vinegar) are used up inside the suppressor tube. you've only got the small holes at the ends for "fresh" solution to get in. meanwhile if it's apart there will be more surfaces exposed constantly instead of it just being the outside of the can.

  • @don_sharon
    @don_sharon Před 2 lety

    Chinesium.... Awesome. Great vid as always.

  • @LaGuns-yo9be
    @LaGuns-yo9be Před 2 lety

    Absolutely incredible video bro! Keep on it my friend. God Bless

  • @SharpShooterCO
    @SharpShooterCO Před 2 lety

    Super interesting stuff... wonder of you you could remove lead from a barrel in this manner.. Thanks as always for the fantastic content 👏👍

    • @jlbksinger
      @jlbksinger Před 2 lety +1

      You can, but you still have the toxic waste to deal with. Been there, done that. Only once.

  • @batmantiss
    @batmantiss Před 2 lety

    Science! Excellent video thank you

  • @chemically_literate
    @chemically_literate Před 2 lety +1

    The white stuff is probably antimony acetate. It is moderately water-soluble and forms white crystals. Also, antimony is very common in lead alloys. As for the suppressor the brown stuff is probably hydrated iron oxide or rust. Not sure if it'll ruin the process tho as the visual can be more dramatic than the rusting damage actually is. I'd like to see you try again with the suppressor and this time reduce the volume of your solution by boiling so the lead would come out more easily (also get's rid of the leftover peroxide).

  • @Glocktard
    @Glocktard Před 2 lety +2

    If I understand correctly, the silencerco omega’s outer serialized thin wall tube can be unscrewed from the core (bother ends off to) and then put the Core into a water rotary Tumbler with stainless steal media to clean the carbon deposits.
    It took me about 6 hours of 3 hot Dawn water baths to clean a Sparrow core, but boy is that thing clean now.

    • @Bill-v650
      @Bill-v650 Před 2 lety

      i believe he said in an earlier video that his has become seized up...

    • @JohnnysReloadingBench
      @JohnnysReloadingBench  Před 2 lety +1

      I can't get mine apart anymore, but it's headed back to silencerco soon. I worry a lot about using the rotary tumbler and getting steel chips or pins stuck in there. I've heard it works awesome, though.

    • @christopherbenfield7848
      @christopherbenfield7848 Před 2 lety

      @@JohnnysReloadingBench Lok at replacing the Omega endcap with the AREA 419 cap and using the adaptors for your rifles. This allows you to switch betwen different thread pitches without touching the can. I use it on almost ALL my rifles and have seen ZERO impact shift between removal and re-install

    • @BFVgnr
      @BFVgnr Před 2 lety

      @@JohnnysReloadingBench on the plus side, the SilCo folks are great about taking care of stuff. I had an end cap strike with my Hybrid and an aftermarket barrel. I contacted SilCo because I wanted to make sure there wasn't damage inside the can I couldn't see. About 3 weeks after sending it to them, it was back with 'no damage found' and a new end cap. That led to a trip to the friendly local suppressor shop where I discovered their 1/2x28XL piston and it's internal 'shoulder' that was designed for thinner pistol barrels that don't have enough metal for a proper shoulder.

  • @Whoadayson
    @Whoadayson Před 2 lety

    Interesting stuff JRB

  • @alexeytsybyshev9459
    @alexeytsybyshev9459 Před 2 lety +1

    The white sediment could either be some poorly soluble lead salts like lead sulfate, perhaps from sulfates in your tap water, or from some other additives in the lead that would form insoluble salts. Maybe antimony?

  • @christopherbenfield7848

    Johnny you have an Omega 300. remove the caps to get more crap out of it by scrapping. Also heat up some water to around 180F and add some limi-shine to it. Not much but around 1-2 TBL spoons. Then submerge the suppresor. WOrks like a charm. I use it on brakes as well.

  • @GrimSkey
    @GrimSkey Před 2 lety

    Would love to see a follow up vid with everything done correctly

  • @stevekiemele995
    @stevekiemele995 Před 2 lety

    You are a renaissance man!

  • @wolf14900
    @wolf14900 Před 2 lety

    I believe the white powder may be the trihydrate form of lead acetate. When lead acetate is dissolved in water it forms the trihydrate.

  • @grabbabitewelfed1641
    @grabbabitewelfed1641 Před 2 lety +1

    Good job , man

  • @ChemistyStudent
    @ChemistyStudent Před 2 lety +7

    Like someone else has said, since you're making lead salts by reacting the lead, copper, etc with the acetic acid I think your best bet is to let it dry out naturally and disposing of the remaining solids with your local special chemical disposal center. That being said, if they won't take it, I'd suggest you mix it with some epoxy.

  • @GS-el8ll
    @GS-el8ll Před 2 lety

    wow you can see the lead crystals starting to try and form even with the dilute solution

  • @GuberShep
    @GuberShep Před 2 lety

    So cool to see NileRed casually mentioned in a gun channel.
    *Hey I watched that one!*

  • @TMS5100
    @TMS5100 Před 2 lety

    epsom salts work as well to precipitate out the lead into lead sulfate.

  • @maybe-Gone
    @maybe-Gone Před 2 lety

    Hi college chemistry student, some info may be off.
    the blue solution looks to probably be cuprous acetate from the copper jackets of the bullets.
    That line that was forming appears to be the separation between the lead and zinc acetate with lead metal floating in between (lighter than lead acetate and heavier than the zinc acetate)
    The orange mist that formed was probably a mix of iron and copper dissolving off the wire holder and inside of the baffles.
    As for the white precipitate I don’t think I know at all why could have caused it other than maybe some weird reaction between an oxide layer on the lead balls
    Cool experiment! Would love to see it tried again, maybe try filtering the precipitates with a coffee filter at the end too?

  • @Johnny-jr2lq
    @Johnny-jr2lq Před 2 lety +1

    @Shannon idk if the piston clean is similar to CLR but that’s what I have heard people using to clean there suppressors and muzzle brakes also barrels ?????? Idk maybe that might work for you

  • @richardstone5241
    @richardstone5241 Před 2 lety +1

    1. REGULAR MAINTENANCE is key to suppressors especially .22 rimfire!
    2. Clean a take down suppressor (I don't like sealed units) as often as you clean the weapon (doesn't allow build up of lead or carbon).
    3. Use brass brush for steel parts and nylon for aluminum.
    4. Apply a light coat of CLP, white Lithium grease or petroleum jelly to internal parts (makes cleaning much easier).
    5. Don't be a pig with your equipment, keep things maintained and enjoy!!!!!!!!!!!!!!!!!

  • @palmervanbuskirk3445
    @palmervanbuskirk3445 Před 2 lety +5

    Jonny, I use two methods to clean suppressors.
    I've found that "The Dip" works great on lead but not so well on carbon deposits. I read somewhere that you can take soda ash (sodium carbonate) and add that to the solution to neutralize the acid and precipitate out the lead. It's often sold as pool pH up at the hardware store. Add slowly and stir gently because it foams quite a bit. I'm not a chemist so I'm not sure this works but it does drop off a lot of the "white dust" into the solution. The blue color in your jar is likely dissolved copper from bullet jackets.
    For carbon, I soak my pistol baffles in a mixture of Lye(sodium Hydroxide) and water for a couple days. The carbon loosens up and can be wiped out or easily scraped off. You could also try firing some 223 rem to blast off the baffles since you can't take your suppressor apart. Lye is not good to get in your skin or eyes so make sure to use safety gear. however it's pretty safe to dump down the drain since it is used often in drain cleaning products. It should not be used on anything aluminum(only steel) as mixing with aluminum produces a toxic gas. It may strip off the finish on painted parts.
    Hope this helps.

    • @luxordeathbed
      @luxordeathbed Před 2 lety

      CLR on carbon deposits. BUT don't leave it in the CLR for a long time as it can damage steel/stainless steel. 10-15 minutes works wonders. Search youtube on CLR on muzzle brakes.

    • @PSUQDPICHQIEIWC
      @PSUQDPICHQIEIWC Před 2 lety

      Sodium carbonate is also sold as "washing soda". After I process circuit boards, I have to wash the etching tank. The rinsewater and the water in the dunk tank contain dissolved copper. I just add an excess of sodium carbonate to precipitate everything. Copper carbonate hydroxide isn't water-soluble.
      I don't know how that holds for lead. I'm assuming that the product would be a basic lead carbonate with low solubility as well. I don't know about the antimony fraction.

  • @shanebrown8406
    @shanebrown8406 Před 2 lety

    You should check out stingerworx suppressors. You can break it down to individual parts and get it clean without worrying about parts inside the can that are hard to get to.

  • @mii3000
    @mii3000 Před 2 lety

    Thank you for making this video. I have been curious about this for a while, but all the information I could find on the web is inconsistent and not trustworthy. I'm still trying to figure out a legitimate way to dispose of sulfuric acid that I used to anodize some AR parts.

  • @luxordeathbed
    @luxordeathbed Před 2 lety +5

    First thing. KEEP this video. It is educational and the more info we have on the dip being "less hazardous" the better.
    I cleaned my suppressors recently and have a batch of the dip sitting around. I have been researching for years how to make it less toxic.
    It seems NaCl (aka salt) would work. I found a chemistry video of lead acetate reaction with NaCl with the chemistry formula, but no actual concrete video. Been told to boil water to make it a super saturated NaCl solution then dump into dip to make Lead Cloride (or is it Lead Clorate?). NileRed I am sub too and saw that zinc vid. Considered it too. I am also partially ready to join his patreon for a month to ask questions he might be able to answer regarding this at home chemistry.
    Still looking for a place in my area that will dispose of lead acetate. Any time I call a hazmat place, I get the question of "what is lead acetate". Morons.

  • @CompShooter54
    @CompShooter54 Před 2 lety

    I watched the video twice, because the first time I didn't see where you did a cleaning with the suppressor in the solution with zinc at the same time. You only put zinc in the solution after the suppressor was taken out. What happens when you put the zinc in with the suppressor, or just lead balls if you don't have another suppresser to clean? Is the cleaning faster? Slower? No change? I clean my compensators with the peroxide/vinegar solution, but would like to see what happens with zinc added during the cleaning. Any chance you will make another video showing this?

  • @justsnuggle
    @justsnuggle Před rokem +1

    Any new updates or Revelations to the suppressor cleaning process?

  • @Frank-pp9iy
    @Frank-pp9iy Před 2 lety

    So cool. Chemistry and guns!

  • @jonathanrogers9961
    @jonathanrogers9961 Před 2 lety

    Really cool stuff! Thank you

  • @stephenfowler4115
    @stephenfowler4115 Před 2 lety

    You can melt the lead zinc mix and the zinc will float on the lead so you can scrape it off.

  • @TAR3N
    @TAR3N Před 2 lety

    Water contamination can play with your end result. Best bet is to use distilled water . Also, the sugar of lead can be used to make pigment ( toxic though ) .

  • @fuser662
    @fuser662 Před 2 lety +2

    Just use CLR, no lead acetate produced. I soak my suppressor for 5 min, rinse with warm water and dry it out in the oven. easy peasy

  • @ThisFish888
    @ThisFish888 Před 2 lety +1

    Lead oxide is white, perhaps the H202 is forming it faster than the vinegar can dissolve it.. idk? would the oxidation be accelerated by including some kinds of salts?

  • @jmkhenka
    @jmkhenka Před 2 lety +1

    Is there really so much lead in the supressor? In my experience, the majority of weight comes from powder residue..

  • @chevrofreak
    @chevrofreak Před 2 lety

    I wonder if the Cobalt and Titanium in the suppressor had any impact on the reactions? Did the Rocksett that holds the outer tube on get dissolved?

  • @lukeclement1310
    @lukeclement1310 Před 2 lety

    Regarding the suppressor solution I wouldn’t think you would get a lot of lead to accumulate on the zinc after the can is removed. Why? Bc your bullets are copper jacketed… the barrel is not exposed to lead unlike a 22 long rifle barrel or can.
    If you ran no or partial copper jacketed bullets then I would assume you would get more lead from a suppressor dip as in that case the lead barring surface is in contact with the rifling instead of a copper jacket.
    I use the dip to clean carbon off my muzzle breaks and the solution turns more dark blue and I assume that’s copper and carbon that has been dissolved.

  • @boughtough
    @boughtough Před 2 lety +4

    Have you thought about getting an airlock like what craft brewers use? That way the hydrogen gas can still get out but even less chance of spillage.

    • @JohnnysReloadingBench
      @JohnnysReloadingBench  Před 2 lety +1

      That's an awesome idea. I'd like for it to evaporate over time, but it would probably be safer to have something spill-proof for long term. Definitely something I'll consider.

    • @mattwheeler702
      @mattwheeler702 Před 2 lety

      Isn't the point of those things just to create like a one way valve to prevent bacteria and whatnot from getting in?

  • @BlackdogADV
    @BlackdogADV Před 2 lety

    I’ve had my suppressor for 6 years. It’s a 22 AAC Element. I just throw the stainless baffles into my wet tumbler and let it run all night. Sometimes I tumble the baffles with my brass. Keep in mine, I have to tumble them for a very long time, 12-24 hours. I don’t use the suppressor all the time because I don’t like cleaning it.

    • @luxordeathbed
      @luxordeathbed Před 2 lety

      I found simple green in a steel pin tumbler for 24 hours worked awesome on carbon. Still had some stubborn stuff, but worked out.

    • @BlackdogADV
      @BlackdogADV Před 2 lety

      @@luxordeathbed I’ll try that next.

  • @ReactionTime344
    @ReactionTime344 Před 2 lety

    Good vid, I like the science!

  • @singleshot2218
    @singleshot2218 Před 2 lety

    Could you disassemble the can afterwards? Maybe to clean by hand?

  • @teeroux
    @teeroux Před 2 lety

    The white precipitate is lead oxide from the peroxide reacting.

  • @trigsim
    @trigsim Před 2 lety

    Since there is more than just lead in the suppressor couldn't this have some other affects? Like there may be a small amount of copper in some form, and powder residue.

  • @calangel
    @calangel Před 2 lety +1

    There was an article on the web about using the dip to clean stainless steel. While it does not appear to cause damage to the steel, it actually does cause oxidation. That's what that brownish colored stuff was. Rust. You rusted/oxidized parts of your can, dude.
    Unless you go to town with cast lead or high pressure exposed-base FMJs, there shouldn't be much of any lead in your can. Use a solution to dissolve the carbon from time to time, and you'll be good.

  • @BlackSoap361
    @BlackSoap361 Před 2 lety

    Junkyard chemistry. This is good stuff.

  • @fomerbu
    @fomerbu Před 2 lety

    Hydrogen gas plus oxygen can deflagrate under certain circumstances. Got me thinking about a new replacement for smokeless powder

  • @daviddiebold7357
    @daviddiebold7357 Před 2 lety

    The white powder is the lead sugar , lead acetate. I’ve read probably the same stuff. the rest is Peracetic (sp?)acid. Don’t melt the sugar that’s the most deadly way . The zinc affected lead ehh I dunno. Also their should be some tin, antimony, silver, and arcinic (sp?) just what was their to start with. Paracetic acid also gets copper so the bronze brass dissolved.

  • @nathanbieber2840
    @nathanbieber2840 Před 2 lety

    This is so cool! Science is great.

  • @ThisFish888
    @ThisFish888 Před 2 lety

    Could you burn the carbon off by making a potassium nitrate solution and then wetting the inside of the can,, and then aftet allowing it to dry and you ignite the carbon with a match

  • @EvilGenius007
    @EvilGenius007 Před 2 lety +3

    I thought build up in suppressors was primarily carbon and other byproducts of combustion. I'd be curious if there was a maintenance schedule of cleaning with only the Piston Kleen (e.g. quarterly or monthly) that would keep things relatively gunk-free.

    • @JohnnysReloadingBench
      @JohnnysReloadingBench  Před 2 lety +6

      That's the plan, as of right now. Piston Kleen and a fresh layer of anti-sieze on threads every few range trips. Hopefully it will make this dip stuff unnecessary.

    • @russr
      @russr Před 2 lety

      @@JohnnysReloadingBench this was a test i did 10+ years ago, to make the baffels easier to clean the next time, if the baffles are removable, heat them up to 150f ish and drop them in a jar of DOT 5 Silicone Brake Fluid over night. then just wipe them off and put them back in. the heat allows it to better "soak up" into the metal pores...

    • @wades623
      @wades623 Před 2 lety

      primers are made of lead fulminate from what i understand so that is where youre getting lead from and why you always see those warnings on ammo boxes and stuff

  • @JainZar1
    @JainZar1 Před 2 lety

    The reason it took so long is because the mixture was too cold. A safe way to dispose of the Leadacetate is to boil off the solution. It turns the lead acetate back into lead-oxide.

  • @jimyeats
    @jimyeats Před 2 lety

    Hey, you should look into Sharp Shoot R No Lead bore cleaner. I have some and if I drop a lead fishing weight into the solution it starts fizzing and has a whitish gray residue that starts coming off in clumps. Has a vinegar/acid smell. Would be curious your thoughts.

  • @quietm4
    @quietm4 Před 2 lety +7

    You are introducing many more elements to the solution, not just lead. The brown color is happening because your solution is oxidizing the steel (aka iron) in the brush you used as a way to remove the suppressor. Oxidized iron is also known as rust...which is causing the brown color of your solution.
    If your suppressor was a dedicated 22lr can, you would really just have lead buildup in the baffles, with a carbon and a little copper (if you shoot copper coated bullets). Since your suppressor is a centerfire can, there really isn't going to be much in the way of pure lead buildup...it's mostly carbon fouling...can't remove a lot of lead if it isn't there to being with.
    I use "The Dip" on my 22lr suppressors...I don't even bother cleaning my centerfire suppressor...especially since I can't remove the baffles. To dispose of my lead acetate solution, I just leave the jar open and let the solution evaporate over time (outside, of course)....only the lead is left in the bottom. I'll try the zinc method next time.
    IMO, cleaning a sealed centerfire suppressor is king of like trying to clean your car muffler. If the suppressor is still efficiently suppressing sound, then leave it alone. Running a carbon cleaner like that piston cleaner seems to be doing something, but if you can't get to the baffles to clean/scrap them, then what is the point?

    • @hyfy-tr2jy
      @hyfy-tr2jy Před 2 lety +1

      something you forget that is a major contributor to fouling with 22LR and that is wax....22LR are lubricated with a fair amount of wax and boy oh boy does it build up

  • @darvinclement3250
    @darvinclement3250 Před 2 lety

    Hey Johnny, I'd be interested to see crushed zinc tablets (the kind you get in the vitamin section) poured the into the solution. I need to clean my 22 can so I'll give it a try when I do.

    • @the1andonlySherlock
      @the1andonlySherlock Před 2 lety +2

      Those probably won't work. You need relatively pure zinc metal in order for the replacement reaction to work, and those tablets don't use pure zinc, they use some type of zinc compound.

  • @keitha.9788
    @keitha.9788 Před 2 lety +3

    Ok, i'm confused. What the heck were you trying to accomplish in this video?? At first I thought you were just trying to clean your suppressor....

  • @nathanbieber2840
    @nathanbieber2840 Před 2 lety

    For the suppressor jar.. Is that because so much carbon is mixed with the lead?

  • @mblake0420
    @mblake0420 Před 2 lety +3

    Look up Cody's lab and ask him, he is a backyard chemistry genius

  • @IWatchedWhat
    @IWatchedWhat Před 2 lety +1

    How about an air lock from home brewing on the bucket?