Sulfur Nitride, My Arch Nemesis - Ex&F
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- čas přidán 7. 07. 2019
- The chemistry in today's video is thanks to a personal grudge against a certain energetic compound made only of sulfur and nitrogen: S4N4. I also explain a heated opinion about a certain part of the visible spectrum.
Patreon: / explosionsandfire
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Twitter: / explosions_fire
Special shoutout to r/yellowchemistry / yellowchem
Nightmare fuel
The paper we are following:
"Tetrasulfur Tetranitride, S4N4"
onlinelibrary.wiley.com/doi/a...
Ok bois are you ready for the long list of patreon names going for a to z?? here we go:::::
Adam Conour
AllChemystery
Aussie Chemist
ChalkyChalkson
Christopher Stillson
Clark Lowe
Corrosion
Craig M.
Dan Kaplan
Daniel Coleman
Elric
emuwarvet
Grant Trent
Gregory Wong
Isaac Paciga
Jacob Tierney
John Libal
killroy225
Leon Schutte
Leon Stark
Luke McGoggan
Michael Kavulich
mirgp, no wait Azide Fox (sounds dangerous honestly)
Mortlet
Nile Red
Oliver Toth (yellow chem loving sinner)
Oz Sabina
Rhodanide
Roger Dot Lee
The Gayest Person on Patreon
Thomas Abbott
Zachary Chapin
Ok what else goes here, maybe some bonus content? Don't have anything really good this video, I didn't do too many stupid things. So i'll try and make up for it in future. This is a clip I cut from a joke that wasn't funny really (also barely made any sense, which is more a reason to cut it than lack of humour, because people complain about things not making sense more (fair enough)) • me hitting a can with ...
see you around fam
Comment 'yellow chem bad' for 7 years of good chemistry luck.
Scroll past for low yields forever
Explosions&Fire2 -
Yellow Chen Bad
Yellow chem bad
yellow chem bad
Yellow chem good !
jokes on you, I do computational chemistry
"it detonates when hit with a hammer in much the same way that carrots won´t detonate when hit with a hammer" god i love The Hitchhicker's guide to the galaxy
Is that a quote from Hitchhikers? (I know he said it in the video, just don't remember if it's from the book)
KingHalbatorix The real quote is:
*”They hung in the air, much in the way bricks don’t”*
The general form is sometimes called a "dissimile."
nightsong81 yes, thank you!
KingHalbatorix it’s from the radio show, not the book. HHGTTG was originally a radio show.
You're like a terrifying chimera of Nile Red and Michael Reeves. I love it.
cody's lab possibly?
Avalon Page BUT BETTER
Dead on. Thanks for the good laugh.
Cody's Lab meets Fairbairn Films.
I was thinking he's more the love child of Nile and AvE!
Our professor put quite a big question about S4N4's structure, synthesis and properties into our entry level anorganic chemistry exam. By pure accident I watched this video the evening before and was able to answer the questions the next day. So you saved me quite a few points, thank you!
I forgot the name of your channel so I typed in google "youtube chemist that hates yellow" and this video was the first result x"D
🤣
You know he's a real chemist because his labcoat is slowly getting holes eaten into it.
Yeah, when I was at uni my labcoat was eaten to shit after a semester.
akkudakkupl You haven’t Carbon engineered something until you’ve caught yourself on fire.
True. Some people in my lab had additional holes in their Coat you could put your arm through, although most just had their sleeves holed.
You know he's a real chemist by the constant stream of "colorful expletives" as he enjoys his "favorite chemical".
You know he's a real chemist because his labcoat is consists of more holes than coat :D
As a physicist...
...fair point
XD
I'm in the physics department, _and_ I work with the bone-hurting juice.
That username is mint, Luigi.
High class- no really, high-class.
God I love the physics department
@@captainjirk9564 Of course you do, strings is part of your name.
The Physics Department joke hits different since he revealed his true allegiances
This was my prof's fav compound, so he made us all make it in the lab. Wish I had my inorganic chem lab manual to give you. It made some beautiful orange needles (2 - 3cm long) that were really unstable.
"Don't do a melting point test on it." *BAM* "What did I just say?!?"
Some folks you just kept to the other size of the lab. =D
I feel like he could've just said "It's an explosive. Don't heat it."
@Toronoc Your professor sounds like the type of person to post two throwaway sentences about it on the internet...
BENZENE is BACK - I knew it was good for something apart from making cancer
The hero we deserve
Benzene to Leukemia I am your father!
@@Barskor1 You meant "Leuk, I am your father!", right!?
@@realedna Yeah that's it! :)
realedna badumtss
Most discoveries in chemistry are not accompanied by "Eureka!", but more usually "that wasn't supposed to happen!". Thanks.
Had a student precipitate some mysterious black crystals once during 1st year chemistry. I was like "dude, HOW, you were supposed to do an extraction, there is literally nothing in this mixture except solvent and caffeine!". Sadly the product was cleaned away, so I never got to check what it actually was :(
@@hamstsorkxxor we also had something like that in the lab, my co-student managed to turn a simple paracetamol extraction blue...
...... Or, "why are my two lab assistants dead?" That happened to the first people to synthesize Dimethylmercury. If you can smell that it has a slightly sweetish odor.... it means you have already received a lethal dose and nothing medically can be done for you. Six weeks later you will be brain dead.
@@tinkertailor7385
Yup, feck that, alkylated group 12 elements are on my Nope!-list.
Ian Bunyan and then followed by a “well fuck now I have to figure out what the hell this is...”
at the royal college of military science, one of the students works out theory of TNT and RDX is far too slow burning, so invents a more reactive chemical compound. The professor looks at it and says its already been looked at, and is highly unstable and its impossible to make. Student goes away and spends six months in the lab trying to prove the professor wrong, then he makes it. A minute later there is a massive explosion in the lab. The professor goes into the destroyed lab and sees the student in shock covered in blood, and quietly says to him, thats as far as I got too.
E&F: "weird ring shape"
My brain at 4 am: "haha Pringle go boom"
If this chemistry thing doesn’t work out, you’ve got a backup career as a video editor. This is the funniest editing I’ve ever seen.
Thanks mate! Spent a long time on the editing for this video, glad you liked it!
@@ExplosionsAndFire Its nearly 8:30PM and parts of this video made me laugh harder than I have have all weekend.
@@gorillaau same here my dude, just stumbled upon this channel and it's some of the funniest content I've seen in a long time
Yeah, the dudes sure got a career Woking with silver halides if ever wants one.
Oh'err, hang on, what?
If you think this is good, you'll also like Michael Reeves
Trust me
You gotta love how often osmium tetroxide is brought up as a reagent when you’re learning o chem for forming diols and the like , and then quickly realize that literally NO ONE in a professional lab will almost ever bother to use something so dangerous. I mean for gods sake, you’re more likely to use sodium cyanide for synthetic chemical research than OsO4.
it's the same with lithal, there are much easier ways to reduce carboxylic acids and esters to alcohols without burning the building down
I don't get why you're dissing LiALH. It's ok. As for OsO4, we just don't use it because it is so expensive
1:01 "Women are more perilous sometimes, than any hi explosive"
As a (very) mature student, doing an M.Sc. in an unrelated subject, I happened to use a wash-room in my uni's chemistry department. In walks this chemistry professor who assumed that I was a colleague, and immediately starts slagging off the physics department. IT'S ALL PERFECTLY TRUE, I TELL YA. This is the best chem demo that I've seen in ages. Eat yer heart out, Nile Red.
This is not the prerogative of only chemists. I was a math and CS student back when dinosaurs roamed the earth, and I distinctly remember one of the physics profs using up five of our allotted one hour(s) on a Cray supercomputer before I got permission from one of the CS profs to kill the job.
This is Deep Fried Chemistry
I love it
I just discovered this channel today. Its the greatest thing on CZcams. I love it!! Its the perfect combination of humor and education. The world needs, this please don't stop.
This is such a rewatchable video, Tom knows what he's doing; memes and chemistry XD
New channel to binge watch, nice.
*spent months on making S4N4
*proceed to light it on fire
S4N4: *BURNED AND DISAPPEARED IN LESS THAN A SECOND*
Dang you should have way more likes and subs. Thanks for putting so much time and effort into this stuff for us to see. Ill try to mention this channel to as many people as I can.
Thank you Integza for introducing me to this guy! This is awesome! Your writing/commentary and editing kick ass!
I feel like I'm on a list for simply wanting to see a chemist lose his mind over a reaction.
I feel like he's on a list.
We're all on a list.
I mean... if I'm on a list, then clearly my country's governments must hand out security clearances like candy...
Mystic Thunder not that kind of list, my child.
@no candy agreed
Iirc the cops came by to check he wasn't making drugs
I know it's an old comment, but I can't scroll past a K2 without saying howdy
Come to think of it... whenever my reactions turned yellow during OChem in College, I was usually hitting 50% yield instead of the expected 80% or better. With lab grade starter materials.
You're right.
This is giving me weird flashbacks of a potassium triiodidoplumbite synthesis, shit turned yellow and my yield at like 40%
@@cyllxx9112 Mine got stuck at the fucking filter and I couldn't get it off.
God that makes me happy I chose physics
He's kinda on point lol.
@@Joghurt2499 Imagine a physicist being happy.
I am watching an online lecture about nitrogen right now and my prof is talking about S4N4 and how his profs used to give it to the students in the lab and how it came to multiple accidental explosions. And he also said it's fairly easy to make, as long as you have S2Cl2 and ammonia and hearing that I just felt the need to comment this
Edit: One semester later I had another professor talk about S4N4 in a lecture. And another semester later (two days ago) I finally did the exam to that lecture where I had to draw one possible structure of S4N4 (there's multiple structures with S-S bonds or without S-S bonds)
I love Chemistry and just found your channel. first video I watched, actually.
really dig the content and production value. keep up the great job, making science interesting
This reminds me of my Physical Chemistry lab at Tufts...”You should end with 3.8 grams of white crystals with a melting point of 98.3 C”....yeah? 8 grams of yellow sludge??
sounds familiar.....smeary brownish-reddish goo that took ages to get out of the friggin bottle....."We got 69% yield!" - " You were supposed to get around 12, check your melting point" .......hmmm....?
Hm, test, if nitration is possible..how? Ah, ok, 45min at 75°C...well if that doesn´t do it...here we go...45°, 50, 55...BAM! ...Uh....was that a positive result?
I got 117% yield of a resorcinarene in a university lab - was quite proud of creating matter!
"and your end product should be roughly 10 grams of bluish crystals"
"how does 8 and a half grams of smelly red shit sound?"
A foul mouthed Aussie Nile Red, Love it, subscribed
He's like me he suffers from I just don't give a fuck anymore syndrome 🤣🤣🤣
nah, Nile Red is a non swearing cross between E&F and nurd rage that appeals to zoomers
What do you foul mouthed Aussie, that's just our fair dinkum Australian language mate!
This is by far the funniest science channel on CZcams that I have ever watched. Idk about you knowledge of chemistry, but your sense of humor is just top notch. Great job man keep it up.
CZcams suggested one of your videos to me the other day. It was the first time I'd seen one of your videos and I have to say I felt a mixture of emotions. Firstly, I was fucking furious. Why? because CZcams's areshole algorhythm hadn't bothered to suggest you before. Secondly, I was pretty darn pleased that it had finally gotten its arse in gear and suggested your videos. Thirldly, I felt... whatever that feeling is that you feel when you find a new channel that you just KNOW you're going to spend a lot of time enjoying. You're fucking hilarious dude, had me in stitches here :D
Try making dichlorine hexoxide (Cl2O6). It's formed by reacting chlorine dioxide with excess ozone. According to Wikipedia, it's a red liquid that is (surprisingly) stable at room temperature. But it explodes when it touches organic materials.
Edit: there's also dichlorine heptoxide (Cl2O7), a colourless liquid formed by the careful distillation of perchloric acid in the presence of phosphorus pentoxide (P2O5 (technically P4O10, but I'm using the empirical formula)).
I've LOVED this entire video. WOW. that intro...just awesome, the editing...on another level, you.....I'm going to stop there.
Seriously, one of my favourites so far. Thanks for doing what you do. Keep doing this mate.
Exactly what I thought this is the first video that I watched and I love this
definitely an insta-subscribe
Easily the most swear words per minute I've heard from a "chemist" in my life. Subbed.
honestly this is to this day the best video you ever put out on this channel. entertaining, interesting, crisp editing and dank memes.
Orange? Nah that's just yellow in disguise
Brown is just dark orange
@@ldub0775 So brown is yellow with a tan?
@@LukasBolini (insert vaguely racist joke about tan asians here)
@@ldub0775 that was......definitely NOT what I was going for
@@LukasBolini i fully understand that but do i care? No!
The physics department😂😂so truee
Back when I was a chemistry undergrad at uni, I was required to examine the microstructure of alumina sintered solgel foams I synthesised as part of my project. Well, as it happened, the one and only SEM was located in the physics department- the 'other side'. So, while carrying these brittle alumina foams laid out on a tray, I strolled over to the 'other side', to be meet with some weird looks.....as though I were an alien life form. They were probably thinking: "a CHEMIST in a PHYSICS department? WTF!"
*met
@@garycard1456 shoulda been like 1:16
Wouldn't Social Science be more disliked? or maybe I'm getting confused with Arts Degrees.
@@gorillaau hating social science is like hating your neighbor when hating physicists is like hating your dumbass brother for being a fraud
I have NO IDEA why CZcams thought I might want to watch this but damn, it was right. Scary. Mate, you have an amazingly engaging presence, it was really fun!
I LOVE the presentation of the videos on this channel!
Team up with spyropyro and destroy the world
I think you meant styropyro
@@d3athreaper100 nah he got sucked into a ps1 and became a fukkin dragon.
@@meme__supreme3373 and now he takes drugs and wants everybody to go on his back like that drugged cupcake rainbow donald duck
Don't forget Michel Reeves
@@meme__supreme3373 this made me laugh too hard
good god i'd be convinced you were cooking meth just by looking at your setups alone i love it
Totally agree about the yellow. Worked in an industrial lab where we made an aniline material. It wasn’t used as such but, would have made an incredible yellow dye.
First of your videos I've seen, fuggen love it. Subbed.
"hey this chlorine smells funny"
"Um I dont think you should even be smelling chlorine through your respirator, but i'm more worried about an unexpected other smell in it"
the youtube algorithm has blessed me. your content is amazing, a great way to present science! Bravo Sir!
I appreciate your dedication friend ur a great chemist this was the video i thought of few ago
The sheer manic energy in these videos is brilliant
The blue flash is BEAUTIFUL! Amazing!
Sulfur flames are some of my favorite flames, the blue is so pretty!
if you like that blue put volcano flames blue Indonesia into the search engine of your choice and select images.
S O C K S Y L I C reeee
It's an extractor for soxalic acid?
Right? How could ya do ma boi the soxhlet extractor like that?
1:15 my new favorite insult
new favorite channel.
love it :)
"Women are more perilous sometimes, than any hi explosive" 1:01
He's right.
Where’s the lie
Thank god CZcams just recommended this channel to
me.. it's amazing
Super! Beatiful! Thank you very much!
Every few months I come back to this video just cuz this is the perfect video to describe your channel. Im not a chemist or anything, but man, this tickles me. Bone-hurting juice! Yellow chem bad.
You are a good chemist... I like your chemistry as well as funny attitude
physicist: "Get wrecked by that cans vector alchemist noob"
I love how high-budget these vids are. The McDonald's soda straw in the distillation setup was muah!
I love this video so much, I realised I had left it open in two tabs.
i remember your rage video from back in the day, it was glorious!
The best part is you figured out how to make pink snow! And I liked the blue explosion/flame. The post-pop sulfur combustion reminds me of a fuel-air bomb, which can be extremely powerful.
Love the personal growth on display
It must be some form of cosmic fate that this dude hasn’t died to colourful death-juice in years of chemistry
praise be
I'm so glad I found this channel! Each episode is a mix of comedy and science.......I LOVE IT!
Holy crap, I laughed so hard during this video. You perfectly capture the struggle of amateur chemistry here! Greetings from Finland.
You know your a better person, uhm... chemist, when you do experiments like this and you don't die during the process, whether from gas asphyxiation, poison, or explosion - usually it's a dramatic explosion! Glad you are still here! I am not a chemist, but I love watching chemistry!
God, mate, haven't had such a good laugh in weeks :D
Modern day chemistry! I love how it’s educational but fused with memes and shitposting that it makes for such enjoyable content!
Didn't know chemistry could be funny, thanks for proving me wrong
I love chemistry and wanted to study it but my teacher just fucked off and never came back now we got this shitty substitude and my grades dropped from A to D
Fuck my life
The channel that I"ve been looking for.
7:49 The can realizes "oh shit I'm out of frame"
I feel the same way about alkyl chlorides. It’s like all the onions I’ve chopped in my life are getting revenge on my airways simultaneously.
That reminds me of organic chemistry II labs. The tears are real
As a chemist i can confirm, never work with the physics department....or the nano department.
What's wrong with nano?
Yeah, nano rocks !! Much of the chemistry i was doing (yes Im a chemist) became much more interesting and having lots or feedback tools so that I could iterate faster to get something workin in a syntesis.
Classicly chemists are awesome at finally creating a method to make something, but suck at determining all its properties, from the molecule level to macroscale.
Psychisists are more precise in determining what they made in a whole range of properties, but see the synthesis as a burden and also suck at repeating a synth. Ever seen a pysisist keeping a logbook on paper, even writing down the ambiant pressure, humitity, time of day, temperature, what sort of illumination of the room was used. batch numbers of chemicals apart from the actual chemical brand/repacker. In what conditions the stuff arrived. How it was stored. NEVER put back a chemical into the container when there is still a bit left on a spatula or beaker etc. Over time (years maybe) a container may be contaminated with a gazilion different things,
Glasware awareness. NileRed had a brilliant example of glassware going wrong during some plasma experiments. Very cool. But stuff like that is more common than I thought when I started doing actual experiments (already as a kid, trying experiments i found in a yellowed old chemistru book).
But this whole issue of the two camps just evaporates when you do nano chemistry and nano materials physics under the same roof.
It forced me (more from the chemistry side) to become more precise and actually now i love using the sweet equipment like SEM/TEM/XPS you name it, and sure also the bulk chem stuff.
And it forced my peers arriving from the more physics side to step up their game and actually make stuff, a pure laser dye for example, and do it again a year later.
On paper it all seems so trivial. But actually doing it is very different, even in a fully equiped lab environment. Sigma Aldrich is not the holy grail, their stuff at least should be analyzed and purified before using it when it fails after try after try.
The chemical lab is there anyway, why not do a destilation and scavenge the last bit of moisture out of it.
So its the best from both worlds.
Nano is here to stay, and a material does not just consist of a chemical.
And yep, also the physic background guys begin wearing the coat after being pissed that stains are there to stay and that washing only creates holes in the fabrics.
Finding comfortable safety glasses is an whole other mission. Those stupid painfull cuvix nose destroyers are not inviting to works with. Yet, hand a eye naked college a cumbersome blastproof faceshield when he/se does not like to wear glasses. The next day they'll have proper ones.
Another nice one is: just keep "spilling" acetone or basicly any other chem onto the box of gloves if they are latex ones. After a few day the boxes will magicly be gone and be replaced by proper nitrile and PE and neoprene ones.
When any viny boxes arrive by accident, repeat the "spilling" and put a large white sticker on the box over the word vinyl, and use a black marker just stating "
PVC (polyvinylcloride, 60-80%, 20-40% PHTALATE derived plastasizers"
And just for the lolz, do a few practice runs of holding ones breath, BUT refrain from taking an inhalation just before you begin counting. Fun. Fume hoods are cool, but can handle only so much.(actually they are a pain in the butt, but yeah)
And when a tube bubbling in NH3 goes wrong you'll have to act. Ignore the stinging pain from the NH3 dissolving into your arms at the localtion you by accident scraped against a wall somewhere. Lube the tubing cut at a slight angle, dont get the lube on the gloves, and fasted the the tubing again but better and resume the procedure. (Teflon tape is awesome, also protecting any parts that cannot nastyness).
Once in a while check the oil in the vacuumpump, make sure its correct. Dont skimp on the two opposing backflow flask to protect the pump and the vacuumdistlilling setup. If some gas (like water) must be captured before entering the pump, also go all the way with a scrubbber, better too large then to small, if only to prevent blockage of gasflow.
Bring a bit of foodgrade epsomsalt and sprinkle it into the coffee/drink of a college. They'll never bring food to the place again.
Jeeeh for science ! Theory AND practical.
Sorry for the rant, it was triggered by good memories.
@@blueredbrick this is the first time that reading a lab advice youtube comment gave me useful informations instead of cancer. Thank you sir.
These videos have great rewatchability.
First vídeo ive watched and i already want a 100k especial
"Doesn't like yellow" sounds like you got a little bit of xanthophobia my guy.
Phobia? It's not fear, it's disgust
hehehe
Just found your channel and I love how passionate you are about chemistry. As someone who wasn't too keen on it I really enjoy your videos and hope to see new ones. You're the real life Rick Sanchez.
The grudge that pushes us further into learning....
Saw this video when you first uploaded it years ago, and I suppose I'm having a nostalgia tour...
This video, because of the grudge energy (unconfirmed power source....but relatable in most circles...) pushed me to finally complete a project that was bothering the back of my brain for years....recycling waste eosin-ethanol product at work back into 100% ethanol (definitely not calling it "reagent 100%", cause I did it in my kitchen....and using a basic spirit hydrometer)
By no means anywhere near as complex of a process, but just wanted to say "thank youfor the push".
Also.... yellow chem definitely bad...
"If you can see a colored haze...you're probably too close without gear....any color, (describing smoke/vapor colors) especially yellow..." - passed on by one of my EMT instructors during our HAZMAT course.
How does this dude not have more then 100k subs, I get everyones not into science but he's funny asf
This guy looks like someone who's doing standup comedy while talking about dangerous chemistry. You've earned my sub.
Subscribing to this chanle comes with free 24 hour surveillance from you local government. 😂
good news i use a vpn upon a vpn upon a vpn upon a vpn
Evanston Conner better news, now the F.B.I, C.I.A, and H.L.S all know your location, thank you Mr. Connor.
I love subscribing to the *chanle*
This is definitely the best E&F video. The yellow chem, the redemption arc, the obscure forum post, the pink clouds.
Why is there a van with a fake brand outside my house
The first three minutes of this video are the greatest chemistry rant ever recorded.
I take it there isn't an O4N4 compound?
No, but there is Se4N4 and Te4N4 which are apparently more explosive... harder to make though. So much ring strain!
Sounds like a challenge for the next time you need to prove you've grown as a person. Or should I include a vague and incorrect summary of a synthesis of one of these to ""motivate" you?
@@ExplosionsAndFire God, I can't even begin to imagine how bad Se2Cl2 will smell. Selenium compounds smell absolutely foul.
Rob Newland *several Te4N4 molecules are typing*
@@ExplosionsAndFire and more stinky to make
Love it when NileYellow drops a video.
Love the woollies foil in the back
The S4N4 looks beautiful though imo (AND YES I LIKE YELLOW CHEM *cries in Palladium*)
Or was that just carrots?
@@nicktohzyu the eternal question
looks a lot like a Pd(0) Suzuki catalyst in solid form
Just replace all palladium catalysts with carrot. If nothing else, at least it'll be cheaper!
@@ExtractionsAndIre also when palladium catalysts turn from orange to brown and black, you know they are no good anymore.
Same thing with carrots. Coincidence???
I think you provide a substantial part on chemistry CULTURE. Please don't stop.
>Things most chemists refuse to work with"
>The physics department
t. PhD in physics
You're insane and I love it.
My dad worked for about a decade with HF and TFE, one of the only in academia. Got to spend a lot of time in the lab with him, several feet back with hands in pockets of course. I learned a whole lot, and he still has a tube of calcium gluconate in his desk B)
I LOVE THIS keep it up man!!!!!! 10/10
Thanks mate!
Local man is FUCKING FURIOUS at the color yellow
I'm gonna keep watching this until it hits 1 million views. Cheers mate.
"What am I doing with my life, I smell like piss and shit and all I have is fucking sulfur" - Ex&F 2019
I love you, doc. You and three others, one, alas is no longer with us, i.e. Chemplayer. You are doing chemistry chemistry, not just mix and match and light and run stuff, even with the light and maybe run stuff! I mean LOVE LOVE LOVE your videos. Keep up the good work and I'll keep on viewing and more than just passingly likely liking
Rumours of our death have been somehow overstated...
www.bitchute.com/channel/chemplayer/
Really good to see you chemplayer😘 thanks for the link. I am officially a member there now under a different name, tho videoless. Undoubtedly ive commented on your works. I will continue to be an avid watcher. Also there is a "chemplayer reupload" on youtube dunno if its you (?)
This channel will... Blow up
How the hell a chemistry channel is so funny? Good job sir