Berkelium in Berkeley (new) - Periodic Table of Videos
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- čas přidán 5. 12. 2023
- We're at the Lawrence Berkeley National Laboratory where the element Berkelium has "come home" for some cutting edge research. More links and info in full description ↓↓↓
With thanks to Professor Polly Arnold and her group for hosting us at LBNL - chemistry.berkeley.edu/facult...
And also thanks to the people at Oak Ridge National Laboratory where we have filmed previously. Learn more about Berkelium production by watching our Californium video: • Californium - Periodic...
More from Oak Ridge: • Trip to Oak Ridge - Pe...
This video also featured Professor Martyn Poliakoff from the School of Chemistry at The University of Nottingham... More about chemistry at Nottingham: bit.ly/NottChem
Videos on all 118 elements: bit.ly/118elements
Support us on Patreon: / periodicvideos
More chemistry at www.periodicvideos.com/
This episode was also generously supported by The Gatsby Charitable Foundation
Periodic Videos films are by video journalist Brady Haran: www.bradyharan.com/
Brady's Blog: www.bradyharanblog.com
Join Brady's mailing list for updates and extra stuff --- eepurl.com/YdjL9 - Věda a technologie
Sir Poliakoff's hair is not shrubbery; it's entropy made manifest and it's a world treasure along with the brilliant man it so wonderfully adorns.
And when we get to the close-up of his hair, behind it is a book called "The Strange Story of False Hair".
lol
The knights of Ni approve of this "shrubbery" now go find the nice small fence an etc to go with it 😋
Let's see who understands this bit..
@@Waterdust2000 Ecky-ecky-ecky-ecky-f'tang-zumboing-blebleblebleblah.
Tree three incarnate
Glenn Seaborg was a genius. He was one of the pioneers of ultramicrochemistry. In 1941 they produced microgram quantities of plutonium and worked out the lanthanide carrier chemistry to handle it. By 1942 they had quantities of plutonium that were visible to the naked eye. By 1944 (!) the production had been scaled up to produce and isolate militarily significant (i.e. kilogram) quantities of Pu239 at Hanford in Washington. The separation process was the same one he and his team used to isolate the first samples, scaled up by a hundred million times.
That's absolutely incredible
Seaborgium.
It feels weird watching these videos now.. I used to watch them just for fun and entertainment, but after having studied the elements to such a degree and put a fair amount of work into them, I almost feel weirdly responsible for watching these videos, like I'm checking in on progress made by a colleague.
I'm nowhere near smart enough or knowledgeable enough on the elements to justifiably feel that way, but I guess all the work I put in to study them has given me an appreciation for the work that's put in here.. I see it less as a cool video, and more-so a proud showing of progress that makes me smile and gives me encouragement.
I genuinely want to see more work done to identify and experiment with the newer heavier elements, because more data means more possibilities.. For me and my silly project, and them.
The crystals blowing apart in mere hours is fascinating, I wonder what future scientists/chemists will be able to observe on smaller timescales with more extreme elements/crystals
Probably not a whole lot considering many of them and their compounds cannot survive too well in the natural conditions of the Earth. Something that's really hard for us to spoof even now.
Even with the very intense radiation, some crystal structures can be surprisingly resilient while others will rapidly be destroyed. I have crystals of berkelium I have yet to publish which were destroyed so intensely by the berkelium that you could see gas bubbles coming off the crystals in real time which were likely gaseous byproducts of the "shrubbery" being rapidly destroyed by the berkelium radiation, while others in our group had relatively stable crystals that lasted several months before being blown apart.
pretty sure that's why astatine as an element cannot be observed; too much energy from its decay causes self-vaporization thus destroying any samples
also, a fellow command and conquer fan, hello
@@aloe7794 Halflife of astatine is some eight hours so the problem is making enough of it to produce a macroscopic amount. We can not make it in bulk because of this.
I absolutely love this channel. I am not a chemist, I possess a very basic (self-taught) knowledge of chemistry and I don't always understand the chemistry or the explanations given in these videos, however, I find them extremely informative and inspiring. They make me wish that I had pursued chemistry to much deeper level when I was younger. If I had had teachers like Professor Poliakoff in my youth, I feel I would potentially have made very different choices surrounding my fields of study and my career path. I hope, one day, to be able to shake your hand, Professor, and to look you in the eye and say "thank you, Sir, for everything you have taught me."
Do you plan on making any videos on compound molecules in the future? Such as Metal-Organic Frameworks or Metallic Hydrogen? I would be very interested to hear what Professor Poliakoff has to say about such, or similar, research.
Couldn't agree with you more.
Great teachers are invaluable.
I would love a follow up video explaining more about the experiments that team did and what was learned from them.
I'll have to look for the paper.
Definitely keep an eye out for when their paper gets published!!!
Yes, I'd love to hear about that too! The description of reusing the same half-milligram of berkelium atoms sounds like particle physicists allocating beam time or astronomers allocating telescope time. It isn't _quite_ at the level of allocating "atom" time, but it feels like it... 🙂
These videos are great.
Great video as always. Though the audio levels on the professor vs. everyone else should've been more balanced.
Glad someone else commented on this. I hope they reupload a balanced version.
@@MelindaGreen Unfortunately reuploads are almost always ignored by the algorithm, which is a huge disincentive
I am a PhD (organic) chemist who has always found the transuranics fascinating, even though I've never had the opportunity to work with them. It's not their radioactivity - quite the opposite. I see that as a huge inconvenience and hazard, not a positive. Their chemistry is fascinating in its own right.
Love this channel
Exciting people having to do experiments againt a half life time limit
cheers
@@periodicvideoswhat happened to the sound?? Had to crankup volume to maximum.
@@deadzioand turn it down when Polly Arnold spoke
The exotic look of Professor Polly Arnold triggered in my mind the image of the highly acclaimed actress Tilda Swinton.
Of course, Tilda Swinton can portray ANYONE but playing Polly would be easy.
Right! And Tilda's Polly character discovers a quantum catalytic process (this is new) to scale up the synthesis of Berkelium to one quarter of a kilogram!@@markiangooley
Desperately cute :)
Exotic??
Yes, like an exotic element.
Transuranic elements are always extremely fascinating
I hope in my lifetime I'll see a photo of macroscopic quantities of Fermium or Mendelevium..
Great video! My son has been working with Berkelium at his lab at FSU. Watching this gives me even more appreciation for what he’s studying.
the intricacies of how the universe makes itself
will never cease to be anything other than
fascinating
Fascinating! I didn’t knew that it was named after the city..
The legendary Alexander “Sasha” Shulgin were from Berckely too ❤
I got to go on a field trip to Lawerence Livermore Labs in Livermore when I was a kid in the 1990s. One of the most amazing places I've ever been to in my life.
I just started as a first year in Polly's group at UC Berkeley and let me tell you, it's been an amazing experience! They don't let first years play with Berkelium, though- just Uranium XD
Glad to see the Prof looking so well!
The periodic table is pretty cool and all. Since this is the project commited to chemistry in general though, i'd love to see you start to branch out of this heavy focus on inorganic chemistry. Series on Organic synthesis, Biochemistry, Analytical chemistry, Physical chemistry, etc. would be highly, highly appreciated. We have this focus on exotic physics like quantum mechanics, astrophysics, cosmology in pop-science, all topics that don't really concern us all too much in daily life (though some exceptions with quantum mechanics). Chemistry is all around us, we ourselves are biochemical systems, but somehow all i see in the most popular media around chemistry is inorganic chemistry and nuclear chemistry.
I'd really love for more people to learn about how molecules are made in a lab, or in lifeforms, what physical and analytical techniques are used to separate them, and how we can determine what exactly we have in front of us. Like, terpenoids biosynthesized in plants, extracted in essential oils, measured through GC-MS to separate and determine them, and how they interact with our bodies, just one example that has so much fascinating stuff going on. I wish a lot more people would get to see how great that is.
Thank you for all the wonderful videos!
I love your sense of humor professor... the best jokes one can make are about themselves. Well done sir
The more you learn and test, the more you know and can explain things. The more you can explain one thing, the more you're likely to explain and understand another. Clever.
Great video, also very interesting that practising is mentioned. Which is in MHO important in almost any experimental science, but not really mentioned.
I will not rest until I see a new video for EVERY element. I NEED MORE
Luckily for you, they have done just that already!
Those coming out nowadays are re-takes on specific elements where there have been new discoveries or other news around them.
Thanks for the update 👍
New video drop! Wonderful Christmas present.
I’m touring Lawrence Berkeley National Lab next week! Very excited for it
How did it go?
13:30 when the stash is running out but the guy is coming over.
PLEASE.... the volume levels!
Great video ; damn FINE info.
Thanks✳️
I know how sad it can be when you're down to your last mg, and how exciting it is when a new shipment is coming.
this was really cool makes me wish I could go back to college and study chemistry at the university of Nottingham
Awesome!
I was also made in Berkeley, and for about 20 years had hair just like the Professor's. At night you have a nice view from the Lawrence Hall of Science of the San Francisco Bay Area.
Polly Arnold used to be one of my chemistry professors!
as someone studying radiochemistry, I always thought that all the chemistry done with the minor actinides was done with samples too small to see. being able to witness even a video of Bk is incredibly exciting, let alone hearing about the potential experiments!
Fascinating!
I loved the book “Discovery of the Elements” and it has a section on transuranic elements in the 1940s and Seaborg.
Also I have the Life-Science book “Matter” which has photos of nearly every element and has a foreword by Seaborg.
You need to read Superheavy by Chapman, you'll enjoy it
@@verdienthusiast3868 thank you, I just purchased it on my Kindle.
What are the interesting things that happen when an atom decays while being bound in a molecule?
The energy may break a chemical bond or cross link to another one. One of the leading fields of study in radiochemistry is to find something that can bind to radioactive materials that can form a stable compound or tolerate the decay energy well. ❤
audio is all over the place in this one, please fix
Thank you 🧪🧪🧪
Great stuff again! Chemistry rules!
When I was at Berkeley Chemistry around 20 years ago, Prof. Poliakoff visited and gave a talk. He seemed like a very kind and down to earth guy, but also sounded incredibly posh. Does he speak with the Oxford accent?
So cool to see Berkeley (and Polly) featured on the channel! As a long time viewer and current organic chemistry PhD student at Berkeley, it always blows me away to see what cool science they’re doing up at LBNL.
Looks like Berkelium249, has a its major decay branch as beta radation. And its daughter product is californium249 as a result, which is mostly an alpha emitter. Usually you have to worry about some high energy gammas these larger atoms do an alpha or beta and these 2 lack that metastable gamma factor, which is nice!
According to wikipedia instead of 249 Bk there is 248 Bk also with a halflife above 300 years and 247 Bk with a halflife of 1380 years , but I guess that is very difficult to produce?
Nuclear chemist here :D You get these Elements by irradiating with neutrons. And the only way to get to a "higher" Element is to have another Isotope do a beta Minus decay. Unfortunatly Cm-247 doesn't do beta Minus (to make the Bk-247), but rather Alpha or spontaneous fission. Only the Cm-249 is a beta Minus Isotope.
You can get up to Fm-256 that way as Es-256 is the last known nuclei doing beta Minus decay. So you irradiate with neutrons to the point where a heavy Isotope does beta Minus, and you get the next Element rinse and repeat (starting from U-238 with a chemical separation at Cm-242). For Curium, you start with Cm-242 and finally the Cm-249 does a beta minus
@@SimonsNuclearchemistry Thank you for the explanation !
Be interesting to see the spectral emissions change over those 330 days
Where did you get that periodic table mug, I really want one.
Wish I had the professor in high-school, I would of learned way more from someone who is excited about elements and chemistry this way.
Hiiii how are you amazing job sir love your videos😊
Sir I would love it work there and work with so little my only problem is what is it so hard to get
It’s so refreshing, seeing that scientist talking about his favorite radioactive element, like it’s a childhood toy….
As a former resident of Berkeley, I use the Berk-lee-um pronunciation without thinking about it but either pronunciation works fine.
There a very similar situation with the two pronunciations for the chief constituents of the hemp plant; canna-bin-oids or ca-nab-in-oids. I've heard top researchers use both in the same paragraph.
If it's based on an American city then it should be pronounced as it's supposed to be. This is just another case of European snobery
Why don't they use Berkelium 247 instead? It has a half life of almost 1400 years, making radioactive decay a negligeable factor. Is it because it's that much harder to make than Berkelium 249?
Nuclear chemist here :D You get these Elements by irradiating with neutrons. And the only way to get to a "higher" Element is to have another Isotope do a beta Minus decay. Unfortunatly Cm-247 doesn't do beta Minus, but rather Alpha or spontaneous fission. Only the Cm-249 is a beta Minus Isotope.
You can get up to Fm-256 that way as Es-256 is the last known nuclei doing beta Minus decay. So you irradiate with neutrons to the point where a heavy Isotope does beta Minus, and you get the next Element rinse and repeat. For Curium, you start with Cm-242 and finally the Cm-249 does a beta minus
I heard berklium can produce in small quinities if play beryllium next to Americium.
Am - Cm - Bk
I watch these because he calms me.
Really cool video and really cool hair.
It's amazing how many studies people do on chemicals that are so difficult to synthesize it is hard to imagine having any practical uses for it, but of course you'll never know unless you look!
Your hair is lovely!
Super facsinating material.
Woah! Every segment has a very different sound volume!
Is that really of box of Persil washing powder in a blue carrier bag on the shelf over Prof Sir Martyn’s shoulder?
i have COVID and i need something else to think. thanks for this video
Question: why do chemists working on these super heavies go in order of # of protons? If the end goal is the island of stability, why not skip e.g., 110-120..?
PLEASE DO A VIDEO ON TRITIUM - THANKS!
California represent! ❤ love this series
California has its moments, but there is a reason we call it West Korea around here. I would never live in Cali personally.
@@Vatsyayana87 You call it that because you're a nutjob?
All irregularities will be handled by the forces controlling each dimension. Transuranic heavy elements may not be used where there is life. Medium atomic weights are available: Gold, Lead, Copper, Jet, Diamond, Radium, Sapphire, Silver and Steel. Sapphire and Steel have been assigned.
How genious is the pan at 3:46 onto the book about hair just as the Professor talks about his being shrubbery. What are the odds?! :D
I noticed that too.
Awesome! ^_^
That’s so cool
how mant elements do you jave left to do.
Hahaha shrubbery! Every video makes me laugh and makes me love learning; bravo!
Wow university of Nottingham you go get that
2:11 I love Hume Cronyn!
Sir which chemical is anti iron?
How does the element lose its half life and becomes a higher element, they said it decays into californium, shouldn't it decay into curium?
Beta(-) decay. A neutron becomes a proton plus electron, pushing the atomic number up by one.
Babe wake up new periodic video just dropped!!
The audio is so off in this....
why don't you guy help me figure out what to put in my homemade ballistics gel to keep it clear and from spoiling besides hydrogen peroxide. the peroxide keeps it clear and preserves it but reacts to the bullets and turns them white and slightly foamy. I was thinking adding chlorine to the water might work instead of peroxide, but I'm not a chemist I could go through trial and error for years or accidently create a toxic mixture or stuff earning myself a Darwin. that's not desirable.
I wish I could hear what is being said.
Amazing!
Something seems off with the audio. It sounds like it's been through CZcams's automatic copywriten music removal.
If Berkeley were somewhere in the UK, pronunciation of the element would be Barklium or somesuch...
Yaayyyy more Nuclear Chemistry on CZcams 🎉☢️
basically a chemistry speedrun
The clock is ticking
Why isn't Astatine listed as a Rare Earth element? @ 10:50
Because it is the halogen group (17)
Californium is more stable but more radioactive than its less heavy counterpart?! Would like to see that paper for sure.
I would guess Berkelium beta-decays while Californium spits out gamma rays.
Edit: Seems Cf does spontaneous fission and spits out neutrons.
Thank you legend
0,5 mg is not a small amount in nuclear chemistry.
Am and Cm also have big similarities to the lanthanides
They're back again
As an American that deals with elements daily and that sells them, I can assure you that I know absolutely nobody who says Berkelium like that, not in my near decade in the elements business. That said, I could see certain individuals saying it jokingly. Lol
I was wondering why they wouldn’t cool down the element to try and prolong half life, but obviously if they don’t do it I supposed it wouldn’t work. So I’d be interested to know why temperature wouldn’t influence the decay. It feels intuitive to think that the less they move around the less chance they would have to decay… thank you
Half life is a measure of the rate of the transformation or "decay" process in the nucleus and is not affected by temperature which is the average energy of molecular vibrations.
With all the shrubbery talk, I'm reminded of the Knights of ⁵⁹Ni.
some rude people might describe his hair as shrubbery? Who in their right mind would be rude to this amazing man?
Should do some chemistry in that cup it’s rotten 😂
what berkelium decay into?
The Bk-249 mostly does Beta Minus to Cf-249 but also (>5%) Alpha to Am-245
thats Cf's halftime?@@SimonsNuclearchemistry
500ug of Berkelium is quite a lot for this rare transuranic element.😮
Yus!
Sounds like the most expensive element in the Universe
not a chemist. so what experiments are the students running?
Its so nice so see the Professor. Please Please try increasing the frequency of uploads and can you guys try a "medicinal chemistry" series