Making Silicone from Scratch

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  • čas přidán 28. 06. 2024
  • In this video I make a simple silicone from sodium silicate and ethanol. The sodium silicate was purchased for this video, but can be easily obtained by dissolving silicon dioxide in sodium hydroxide.
    This is my first real foray into polymer chemistry, and as you chemists know, this is about the simplest possible example. I started so simply because I'm unsure whether there is any real interest in polymers, and I'm more than happy to try something more complex if there's any interest.
    Just let me know!
    #chemistry #science #hydrogen #gas #elements #fire #chemical #industury #color

Komentáře • 197

  • @DangerousLab
    @DangerousLab Před 17 dny +126

    80% Random ball throwing content 20% Actual chemistry experiment 🤣

    • @memelord_699
      @memelord_699 Před 17 dny +16

      I stopped listening to any of the chemistry as soon as he started bouncing the balls LOL

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +18

      LMAO Yeaah it was a fun project but considering how simple the reaction is I realized 90% of my footage ended up being just me throwing the thing

    • @horuswasright
      @horuswasright Před 16 dny +1

      And a hundred percent reason to remember the name!

    • @cezarcatalin1406
      @cezarcatalin1406 Před 15 dny +2

      @@integral_chemistry
      I assume the sodium ions remain stuck inside the silica?
      How about use an alkyl ammonium salt that can be liberated as a gas when ethanol is added?

    • @BillAnt
      @BillAnt Před 8 dny

      ​@@integral_chemistry - Gotta have the right silicone "fillers" between the "good" stuff. wink-wink :D

  • @williamackerson_chemist
    @williamackerson_chemist Před 17 dny +54

    This is such a PERFECT video for people to actually replicate as their first home chem project

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +17

      Right? I've been wanting to do more accessible stuff lately as I realized I've been straying into projects no normal person would ever be able to put together at home, and the initial point of the channel was to try and make chemistry more accessible 😅

    • @BillAnt
      @BillAnt Před 8 dny

      ​@@integral_chemistry - Next up: Making silicone-meth-oxide lol

  • @Nighthawkinlight
    @Nighthawkinlight Před 15 dny +14

    This is excellent. I had no idea silicone could have such a simple synthesis. I might have uses for this reaction. If I use it I'll be sure to cite your video. Thanks!

  • @Embassy_of_Jupiter
    @Embassy_of_Jupiter Před 17 dny +53

    so you're telling me sand+drain cleaner+booze makes a bouncy ball?

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +25

      Yessir! I almost did this video starting from sand but I decided to keep it short

    • @redpandah3309
      @redpandah3309 Před 15 dny +11

      Please make it from sand (it would be so cool)​ @@integral_chemistry
      Or make it a CZcams short

    • @JohnathanSammer
      @JohnathanSammer Před 14 dny +2

      you should try heat treating it, maybe it melts it together stronger!

    • @JohnathanSammer
      @JohnathanSammer Před 14 dny +2

      do the reaction inside of acetone, and maybe it connects better when the acetone evaporates.

    • @bairfamilyfarm1336
      @bairfamilyfarm1336 Před 6 dny

      He's telling you not to be a drunk plumber working in a beach house.

  • @experimental_chemistry
    @experimental_chemistry Před 17 dny +18

    In our childhood we had bouncy balls called Flummi, which never made any sense to me: too hard to play with it indoors (they are able to smash every glass into pieces easily) and too bouncy to play with it outdoors (they always bounced away to places where we never found them again...).

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +1

      Those sound exactly like this one honestly. I believe we had something similar growing up, where the most rigid balls bounced way too far and always got lost lol

    • @nicfab1
      @nicfab1 Před 16 dny +1

      The trick is not having glass randomly standing around outside of a cabinet, or inside the room you play in at all

    • @experimental_chemistry
      @experimental_chemistry Před 16 dny

      It's also possible to destroy a showcase glazing with a flummy - believe me, I know what I am talking about: I have got two kids at home... 😉

    • @verdatum
      @verdatum Před 2 dny

      "Super bounce balls" were usually a different rubber; I believe polybutadiene.

  • @experimental_chemistry
    @experimental_chemistry Před 16 dny +8

    Had to try this out - but the mixture was way too brittle (just like coarse wet sand) to form a ball from it... 🙁
    At first I had the impression that the silicate was simply precipitated rather than polymerized.
    But then the texture and name seemed very familiar to me: Dimethylsiloxane is a defoamer that is used against flatulence.
    The crumbly substance felt the same between my fingers as the tablets in my mouth when chewed.
    Of course, I would strongly advise against making your own medication. Here unreacted silicate can lead to life-threatening complications in the digestive tract. But I couldn't figure out how to make a bouncing ball out of it instead when I copied it.🤷‍♂️

    • @integral_chemistry
      @integral_chemistry  Před 8 dny +1

      I did a good deal more research over the last week and I'm fairly confident the mechanism from the literature I posted in the video is wrong. My best guess at this point is that it is cross-linking, but the cross-links are Si-O-Si with sodium ethoxide acting as a leaving group. However, that's just what makes the most sense to me. I've seen tons of other totally plausible ideas thrown around here in the comments. I do think the wet sand analogy is pretty accurate too, and I think I downplayed just how much persistence you really need to force that crap into a ball. It does work eventually though! Just really have to be patient

  • @queazocotal
    @queazocotal Před 17 dny +19

    On the 'slow to cure' caulks, It can be fun to play with these. The acetoxy cure silicone cures by releasing acetic acid and absorbing water from the environment. If you mix rapidly with various damp alkali, you get interesting behaviour, from simply setting rapidly, to making a foam if you use a bicarbonate salt.

    • @kerrimtthefrog1001
      @kerrimtthefrog1001 Před 17 dny +6

      Well now you’ve gone and given me so many ideas!
      The old KOR Chanel had a “make your own rubber” and I’ve rescued some critical projects at work with it. I’m sure this could add insulative (I’m not sure about the spelling there) properties for some other tasks like freeze drying chamber seals!

    • @daliasprints9798
      @daliasprints9798 Před 17 dny +4

      The foam idea is very interesting. In FDM 3D printing we use RTV silicone to produce custom insulating socks. Making the silicone foam as it cures might further enhance insulation properties.

    • @SianaGearz
      @SianaGearz Před 6 dny

      @@daliasprints9798 I don't think the heat leakage through silicone sock is that high. Most of the heat loss in an already insulated hotend even with shitty insulation occurs due to expelling the melt to actually print things. Besides floppy fragile sock is inconvenient.
      I do like this synthesis method in this video. If it produces silicone which is high temperature stable and more on the rigid side, i might use it to produce a sock.

    • @daliasprints9798
      @daliasprints9798 Před 6 dny

      @@SianaGearz That's actually not the case. I use MPC heater control where the model is accounting for where the power goes, and only up to 25W goes into flow, while 55-80W (depending on CPAP power level) goes into the air (120W cartridge).

  • @LabCoatz_Science
    @LabCoatz_Science Před 17 dny +25

    I actually made a video a few years about "turning glass into slime", lol. Wish I had known about this process, because I basically just precipitated silica gel from my sodium silicate and called it good. This would've been much better!

    • @domsquaaa4323
      @domsquaaa4323 Před 17 dny +1

      .

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +3

      I think I saw that one! I considered also starting from glass/sand but decided to keep the video short. But yeah I feel this reaction isn't crazy well known considering how simple and accessible it is. Definitely be cool for a high school lab

  • @voinea12
    @voinea12 Před 12 dny +4

    You are the first to make silicone on video, also didn't know it was this easy

  • @shrivanth6774
    @shrivanth6774 Před 17 dny +16

    That's motivating to do more home chemistry

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +2

      Glad to hear it! I've been wanting to do more videos on things people could more reasonably (and safely) do at home

  • @DownToNerd
    @DownToNerd Před 17 dny +4

    Hey man, just wanted to say you kind of cracked open the world of chemistry for me and i love you for that, thank you.

  • @adamrak7560
    @adamrak7560 Před 17 dny +9

    Are you sure you are producing oxygen as a side product?
    To me it looks a bit sus that you are making Si-C bonds that easily. It looks more like Si-O-C, which would not produce oxygen gas, and is thermodynamically more favorable too.

    • @STRA1GHTAHEAD
      @STRA1GHTAHEAD Před 13 dny +3

      Totally second this. I can see ethanol linking like C2H5-O-Si, but I do not see the CH3 end deprotonating like that.

    • @integral_chemistry
      @integral_chemistry  Před 8 dny +2

      Yeah I think the mechanism from my source is wrong. Gave it a closer look, considered the comments and did some more reading and my best explanation of the reaction is that the cross-link is Si-O-Si, with the ethoxide acting as a leaving group on the Si atom. Best I have for now, but a lot of comments have proposed many other ideas that also may be correct.. Honestly the lack of bubbling should have been a giveaway that no oxygen was produced, guess I just got too excited someone else did the mechanism for me lol.

  • @belgiumball2308
    @belgiumball2308 Před 12 dny +4

    You sound like nilered combined with thatchemist
    And I love it

  • @FUZxxl
    @FUZxxl Před 17 dny +44

    Wait... it's that simple? Now I wonder if any medieval alchemists managed to make silicone that way. The ingredients have been readily available for centuries.

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +12

      I hadn't thought of that but maybe. I'm curious now how long ago they discovered that you could dissolve silicon dioxide in lye.. that would definitely be the tougher part I'd think

    • @nolanwhite1971
      @nolanwhite1971 Před 17 dny +11

      I doubt it. We have the distinct advantage of good pure reagents these days. That's relatively recent. They certainly didn't have pure ingredients in the middle ages.

    • @mduckernz
      @mduckernz Před 17 dny

      @@nolanwhite1971Lye, silica, and ethanol have been available in high purity for quite some time tho

    • @FUZxxl
      @FUZxxl Před 17 dny +7

      @@integral_chemistry Earliest reports of dissolved silica goes back to the 1500s, though waterglass was only properly studied in the 1800s.

    • @adamrak7560
      @adamrak7560 Před 17 dny +3

      @@nolanwhite1971 alchemists' had quite pure H2SO4 for a long time, but I am not sure about NaOH. Most old NaOH/KOH making processes are heavily contaminated with NaCO3/KCO3, good for soap making, but would produce contaminated water glass, which can be cleaned but I don't think they knew or cared much. They had really pure 96% alcohol though, but they did not have any 100% ethanol.

  • @Dexaan
    @Dexaan Před 17 dny +1

    As a kid, I loved throwing bouncy balls to confuse my cat at playtime.

  • @waltonchan3931
    @waltonchan3931 Před 17 dny +3

    Love the polymer chemistry, great video!

  • @Tower0fHeaven
    @Tower0fHeaven Před 12 dny +1

    Great video

  • @arbitraryobjective4904
    @arbitraryobjective4904 Před 16 dny +1

    Awesome!! Thanks for the upload!

    • @arbitraryobjective4904
      @arbitraryobjective4904 Před dnem

      I have tried this a few times now and I can’t get it to turn solid. I’m using waterglass I made using potassium hydroxide and silica gel and everclear 🤷‍♂️

  • @fmdj
    @fmdj Před 17 dny +3

    Yes, very interesting! I was so excited when I discovered waterglass. I looked for tons of ways to use it, but I didn't know about this one, it's great!

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +3

      I'm still trying to think of more applications considering what a neat and easily accessible chemical it is! So far I've got this and growing a chemical garden

    • @fmdj
      @fmdj Před 17 dny +1

      @@integral_chemistry that's pretty cool already! This is not exactly chemistry and maybe more something like materials engineering I guess, but I have been playing with using waterglass as a structural adhesive for binding and rigidifying carbon fiber for high temperature applications and I'm pretty sure there is potential there. Probably a question of finding the right waterglass formulation and additives... what I've tried seemed promising but kinda reverted to NaOH after a while...

    • @zenongranatnik8370
      @zenongranatnik8370 Před 17 dny +2

      I work in a waterglasses factory and you wouldn't believe how many industries use them. For an amateur chemist though it can be used for the chemical garden, as a raw material for making pure silica, to make homemade silica gel, for glueing and fireproofing reaction apparatuses, for metal casting and many other applications.

  • @chemnobeliumlab1520
    @chemnobeliumlab1520 Před 17 dny +2

    wow that was a legend direct reaction. well done :)

  • @edeniaAJ
    @edeniaAJ Před 13 dny +3

    Cooool! I'm definately going to try this some time!
    I have an idea: If you screw around with the ratios a bit, can you in effect modify how much the silicone gets crosslinked? :D

    • @integral_chemistry
      @integral_chemistry  Před 8 dny +2

      In theory yeah definitely! I used a big excess of ethanol here, no idea what would happen if I cut the amount back significantly. My gut says it would be really gooey

    • @edeniaAJ
      @edeniaAJ Před 5 dny

      @@integral_chemistry aha! So then, if you were to reduce the ethanol slightly, could you in theory make a silica gel (which is what this technically is), that mimics industrial silicone?

  • @geordonworley5618
    @geordonworley5618 Před 15 dny +1

    I would love to see more polymers. I am interested in making bio polyethylene and polypropylene.

  • @sunmoon1234
    @sunmoon1234 Před 8 dny

    Silicone glue used as glass aquarium adhesive is acetate based, and gives out vinegar smell when curing by reacting to h2o from moisture in air. It is pet safe.

  • @TheVideoGuardian
    @TheVideoGuardian Před 17 dny +1

    Definitely a useful material. I wonder how much the process could be adapted, such as producing a slower curing pourable mix, or maybe making a gel or a foam?

    • @eclectichoosier5474
      @eclectichoosier5474 Před 17 dny +1

      I wonder how well alcohol would permeate without agitation. Could put the sodium silicate in a mold and add the alcohol on the surface. Or more likely, use this to make thin sheets.

  • @Rostov_med90
    @Rostov_med90 Před 3 dny

    Thanks

  • @evilkidm93b
    @evilkidm93b Před 9 dny

    This is fantastic! Can you comment on the health hazards of this experiment and its products?

  • @Psychx_
    @Psychx_ Před 17 dny +4

    How would the material properties change if ethanol is replaced with 1-propanol? More elasticity and bouncyness? A less dense material?

    • @integral_chemistry
      @integral_chemistry  Před 8 dny +1

      I tried using a few different types of alcohol with mixed results. I did a bit more research since posting this and I believe the actual mechanism is the formation of sodium ethoxide which then acts as a leaving group forming Si-O-Si bonds as the crosslink.

  • @niconeuman
    @niconeuman Před 17 dny +1

    Very interesting! What would happen if you use a longer alcohol for linking? Something like polyethylene glycol?

  • @CaseyNixa
    @CaseyNixa Před 9 hodinami

    Cool! I’ve always wanted to make my own silly putty. I wonder if this would be the first step to that process.

  • @carlospinheirotorres9499

    Great one, extremely usefull stuff - thanksfor taking the time ♥️ btw, by starting with sodium metasilicate pentahydrate (Na2SiO3·5H2O), would that make the process simpler by starting with a solid substance (I have it like little pearls) and only the water content of ethanol (I have the most common, readily available type, which has less than 4% water content)?

  • @WeebRemover4500
    @WeebRemover4500 Před 17 dny

    i remember when i mixed NaOH sol with SiO2 kitty litter, i would usually find a thick disc of some kind of SiO2 polymer at the bottom, it was quite heat resistant. some crude aerogel

  • @mikeguitar9769
    @mikeguitar9769 Před 10 dny +3

    I think it is adding sidechains, not crosslinking.
    CH3-CH2-OH + Na2SiO3 →
    CH3-CH2-O-NaSiO2 + NaOH

    • @integral_chemistry
      @integral_chemistry  Před 8 dny

      I did a good deal more research over the last week and I'm fairly confident the mechanism from the literature I posted in the video is wrong. My best guess at this point is that it is cross-linking, but the cross-links are Si-O-Si with sodium ethoxide acting as a leaving group. However, that's just what makes the most sense to me. I've seen tons of other totally plausible ideas thrown around here in the comments.

  • @alex-mzlzl
    @alex-mzlzl Před 17 dny +2

    Daaaamn i'll give this a shot when back home

  • @Salt_and_Peroxide
    @Salt_and_Peroxide Před 17 dny +4

    cool

  • @LeonelLimon-nj7tu
    @LeonelLimon-nj7tu Před 8 dny

    Can add pressure reactive Photovoltaic material, and it will light up every bounce

  • @randyschoenbeck3630
    @randyschoenbeck3630 Před 6 dny

    That was interesting can we get one with the acetate variant?

  • @MissionSilo
    @MissionSilo Před 17 dny +1

    I need this

  • @yourdemond
    @yourdemond Před 16 dny

    I would like to know more about platinum cure silicone . as well as how to stop cure inhiation like how/what's in inhibitx . thank you for a great video

  • @guytech7310
    @guytech7310 Před 17 dny +1

    Video with the acetate method. DIY Silicon Caulk!

  • @zenongranatnik8370
    @zenongranatnik8370 Před 17 dny +1

    Sodium metasilicate (crystalline Na2SiO3) isn't usually sold to regular customers as it is because it's corrosive. If you bought your waterglass at a hardware store, it probably is an amorphous silicate variant much more rich in silica which is safer to handle. It is also good for making bouncy balls, though. When I was in middle school I used to make them all the time from silica-rich waterglass and denaturated alcohol. Now I wonder what happens if I use metasilicate.

    • @integral_chemistry
      @integral_chemistry  Před 8 dny

      Huh very good to know! Very much appreciate the input from people who know more than me. Interestingly enough though I did make crystalline metasilicate myself which I actually tried first. The result was a think slime that didn't really hold its shape. Definitely cool in its own way, but I felt not as interesting for the video lol

    • @zenongranatnik8370
      @zenongranatnik8370 Před 8 dny

      @@integral_chemistry Seems right. When dissolved in water, metasilicate gives mainly isolated (SiO3)2- anions but the more silica in waterglass, the more polymeric the anions become. Long silicate chains probably work better in creating bouncy balls.

  • @IlusysSystems
    @IlusysSystems Před 17 dny +2

    Neat, I didn't really understand silicone polymerization mechanism (not that I tried, but still). I see, that during actual polymerization the silicone loses water, but I am wondering, what prevents single silane molecule to lose water and become like ketone (dimethyl silanone). And if it does only tiny bit, why is this not preferred.

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +1

      I'll be honest I'm still struggling to understand this mechanism myself. I tried for a while last night to put my own version together but I couldn't balance it, nor explain electron movement. In the end I just gave up and copied the mechanism from the literature.
      I'll probably just post a link in the video description and see if anyone else can figure that one out

  • @nachodealfonso5934
    @nachodealfonso5934 Před 17 dny +3

    How can Si-O bonds turn into Si-C bonds from Na-silicate and EtOH? I think there is something wrong with the mechanism, and no cross linking could be explained like that either. Could you provide any reference? Thank you for all the chemistry on this channel!!!

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +1

      No problem at all! And yeah I spent about an hour last night toying with this reaction to try and make it make sense to me, as I always assumed cross-linking could only be achieved by acid hydrolysis. In the end I just decided to copy the mechanism from my source instead of trying to make my own..
      Anyway yeah I'll try and put the link in the video description, maybe someone else can sus it out.

  • @daliasprints9798
    @daliasprints9798 Před 17 dny +1

    What reaction is used in RTV silicones?

  • @jeremiquirus1958
    @jeremiquirus1958 Před 17 dny +1

    Hey what is the song that starts playing at the end?

  • @TheOpticalFreak
    @TheOpticalFreak Před 17 dny

    Cool! 😁😃 So how does high heart resident silicone work!?

  • @verdatum
    @verdatum Před 2 dny +1

    Now please explain platinum-cure versus condensation-cure (tin-cure) silicone polymerization. Because both mystify me to no end.

    • @integral_chemistry
      @integral_chemistry  Před 2 dny +1

      I might need to do some homework on that myself 😅 polymers are an enigma to me much of the time

  • @SoylentGamer
    @SoylentGamer Před 17 dny +1

    i wonder if you could make phenolic silicone, and what its properties would be

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +2

      I might have to give that a try! (Or at least read into it first). Tbh I know a lot more about carbon-based polymers than these silicone ones, but this project has definitely gotten me interested

  • @CarterSchonwald
    @CarterSchonwald Před 16 dny

    How’s these approaches compare to tin and platinum cure silicone?

  • @geoffbeyrent6950
    @geoffbeyrent6950 Před 17 dny +1

    Does this mean that this compound can be distilled with heating to collect copious amounts of formaldehyde?

    • @nosurprise885
      @nosurprise885 Před 17 dny +1

      It might polymerize right away because of the temperature

  • @Flare1107
    @Flare1107 Před 13 dny

    Is the polymerization linking process not temperature dependent? If small, or dilute volumes of chilled catalyst were added slowly, to chilled base, could this extend the chain length Giving a lower durometer?

  • @imikla
    @imikla Před 17 dny +1

    How does this relate to silicone lubricants.

  • @brooksbryant2478
    @brooksbryant2478 Před 17 dny

    What happens if you replace the ethanol with a different alcohol, like methanol or isopropanol?

  • @johnslugger
    @johnslugger Před 6 dny +1

    *Better to use Acidic Acid.*

  • @grilsegrils9330
    @grilsegrils9330 Před 11 dny

    Hi, why is some silicon sweating some sticky substance when aging? Typical found on things like salt and pepper grinders and many other items with this type of silicon used

  • @goryao
    @goryao Před 17 dny +2

    Where did you hear that you can put alkanes into silicates like that? I am pretty sure what's going on is alkoxide formation with the ethanol, which then condense with silanols.

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +2

      I think you're right.. honestly I just took the word of a paper I found and when I couldn't make the mechanism work myself I just figured the author knew better than I did. Should have added some disclaimer about my uncertainty.. I'll look into it a bit more but your idea sounds much more feasible as a mechanism.
      Weirdly there's not a ton of info on this process despite it being so simple and accessible

    • @goryao
      @goryao Před 17 dny +1

      @@integral_chemistry Ah yeah, I was wondering if there was something I missed, would be neat to turn Q groups into T or D groups like that...

  • @JohnAltenburg
    @JohnAltenburg Před 17 dny +1

    This reminded me of the movie FLubber.

  • @flyingshards595
    @flyingshards595 Před 17 dny +1

    What would happen if you used sugar alcohols instead of ethanol?

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +1

      I don't think it would work tbh. I tried a few other alcohols and each time I just got a sort of noncohesive slime.. which I guess was cool in it's own way tbh

  • @bigmouthstrikesagain4056

    I suppose you could put it in a mold and press out all the excess water and alcohol and have something that's really rigid but also easy to make

    • @bigmouthstrikesagain4056
      @bigmouthstrikesagain4056 Před 3 dny

      All you need is diy water glass from sand and possibly potash
      (potassium hydroxide?) and diy ethanol which can be made using the same method as prison white lightning

  • @paarsenathan6087
    @paarsenathan6087 Před 16 dny

    I don't know if it's too dangerous or anything. But can you make mustard gas one day. And I mean actual mustard gas cus most people make chlorine gas instead. Like not a whole lot but if you can't becaue it's too dangerous I understand.

  • @lautaromorales2903
    @lautaromorales2903 Před 16 dny +1

    how tf carbon gets reduces and oxidizes oxygen. And no gas was seen being generated

  • @JohnathanSammer
    @JohnathanSammer Před 14 dny

    HE KNOWS MORE THAN WHAT HES TELLING U.

  • @jacobe2995
    @jacobe2995 Před 2 dny +1

    how can I use this in a mold? seems like it's not possible if you have to squees the water out and it hardens when you do.

    • @integral_chemistry
      @integral_chemistry  Před 8 hodinami +1

      I'm not sure, haven't tried. It is still reasonably workable just before it starts to coagulate into a ball. Could maybe work it into a mold around that point

  • @Panda_Gibs
    @Panda_Gibs Před 16 dny +3

    That tidbit about acetate in caulking silicone has solved the mystery of why I thought the stuff smelled like pickles.

    • @integral_chemistry
      @integral_chemistry  Před 8 dny +3

      Honestly when I did the research for this project last week that was the first time I made the connection myself.

  • @rkirke1
    @rkirke1 Před 16 dny

    So what you're saying is Tesla could have used silicone insulation instead of Gutta-percha!? The starting materials are so simple - sand, lye and alcohol, I'm surprised it wasn't discovered earlier!

  • @aaandis
    @aaandis Před 9 dny

    2:24 could you please explain how the silicon-carbon bonds are formed by reaction with ethanol? Looks fishy to me.

  • @camj4631
    @camj4631 Před 17 dny +1

    Please explain to me how ethanol can crosslink your polymer? it looks like you are making and partially hydrolysing tetraethoxysiloxane?

    • @camj4631
      @camj4631 Před 17 dny +1

      Also you do not have any Si-C bonds as far as I can see, does this qualify as a polysiloxane?

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +3

      That's actually a good question.. let me go back to the little paper I found on this and see if I can come back with a good answer. Technically this was from what looked like a undergrad-level lab activity, and I wasn't actually able to find any formal literature on this reaction.
      I'll look into it a bit more and see what I can find

    • @camj4631
      @camj4631 Před 17 dny +1

      @@integral_chemistry you can use cyclopentadimethyldisiloxane (dimethicone) and some catalyst to do it pretty easily :) nit/lice removal solution is mainly that

    • @integral_chemistry
      @integral_chemistry  Před 8 dny

      I did a good deal more research over the last week and I'm fairly confident the mechanism from the literature I posted in the video is wrong. My best guess at this point is that it is cross-linking, but the cross-links are Si-O-Si with sodium ethoxide acting as a leaving group. However, that's just what makes the most sense to me. I've seen tons of other totally plausible ideas thrown around here in the comments.

  • @0GregorSchultz0
    @0GregorSchultz0 Před 17 dny

    honestly....didn't know that a "modified Silane" is still more or less silicone...
    I'm a boatbuilder and a lot of "marine-grade (/-fit) polymers are silanes....like "bostik" or "Sika-Flex"
    kinda shook thats its still basically silicone....sure there are differences but its always like "no don't use silicone, use this-and-that"
    chemically at least similar....very interesting
    care to make a video on the "marine sealants/ caulks"? I for one would find that highly entertaining :)

    • @mduckernz
      @mduckernz Před 17 dny +1

      Yes, so many plastics are just slight variations on side chains used. Sometimes they can have quite dramatic effects!

  • @user255
    @user255 Před 17 dny

    I tried this with potassium silicate, but it didn't work.

  • @michaelpineiro533
    @michaelpineiro533 Před 17 dny +2

    So that's why silicone caulk smells like vinegar.

    • @integral_chemistry
      @integral_chemistry  Před 17 dny

      Yes exactly!^ I didn't even know why until I did this video

    • @ruben_balea
      @ruben_balea Před 15 dny +1

      @@integral_chemistry What do they call it there? In Spain and Portugal it's called acetic silicone, on other countries it's labeled as acidic silicone, acid silicone or even acetoxy silicone. It's much cheaper but causes many metals to rust and therefore damages mirrors, electrical and electronic components and it hardly sticks to concrete surfaces.
      The other is known as neutral silicone or acid-free silicone.

  • @test-uy4vc
    @test-uy4vc Před 17 dny +4

    Im completely new to chemistry and would like to know where to start to know how to produce these things. Any videos, playlists or books would be very helpful! 🤔

    • @chemnobeliumlab1520
      @chemnobeliumlab1520 Před 17 dny +2

      hey buddy as have mentioned that you are a newbie to the chemistry land! I have some suggestion books along with videos.
      The first step is you have to understand what is chemistry and what is not, get used to its language and how to perform stoichiometric calculations.
      For this I can suggest you to either study the Mortimer or Silberberg general chemistry books. You can read the book in your native language or English edition. This is optional due to which language do you prefer.
      The second step is really wide and covers many branches like Organic chemistry, Inorganic chemistry, Analytical chemistry, Physical chemistry etc.
      you can study on these branches but remember that this is not meaning that you can cover every topic. Choose which one you want and which one do you like.
      The third step also exists but it is based on academical research in or out of the university as PhD or post doc.
      For example most of the CZcams dudes do Organic chemistry. Like Apoptosis.
      For the videos I know a few channels covering chemistry :
      Nile Red [Mostly Organic chemistry]
      NurdRage [Amateur available methods and experiments chemistry, Inorganic and some time Analytical chemistry]
      Thy Lab, Lab coats [Both are mostly organic but second covers some cool physics stuff]
      The periodic videos [Covers almost whole periodic table elements explanation + some other cool explanation]
      Apoptosis !!!!
      etc.
      This list goes on and I was tried hard to remember the channels that I have visited recently.
      Also you can check out mit open course.

    • @bedlaskybedla6361
      @bedlaskybedla6361 Před 17 dny

      Try Sciencemadness forum, this is great place where to learn chemistry (not just organics, practically every field of chemistry is covered there). Community is very friendly and helpful.

    • @test-uy4vc
      @test-uy4vc Před 17 dny +1

      @@chemnobeliumlab1520 Thanks! 👍

  • @stevengill1736
    @stevengill1736 Před 6 dny

    Ooooh, that's why silicone seal cures releasing acetic acid...
    The other type smells basic, so must have an amino leaving group....

  • @chemicode
    @chemicode Před 17 dny +2

    Hey Apoptosis wanna join a discord server I made for science youtubers only?

    • @integral_chemistry
      @integral_chemistry  Před 8 dny

      Sure! What is it called?

    • @chemicode
      @chemicode Před 8 dny

      @@integral_chemistry go to my community and the link will be there

    • @chemicode
      @chemicode Před 7 dny

      @@integral_chemistry it's called The Chemtubers

    • @chemicode
      @chemicode Před 7 dny

      @@integral_chemistry uh everytime I tell you youtube deletes my comment lol

  • @mikegLXIVMM
    @mikegLXIVMM Před 14 dny

    2:38
    Why not remove the sodium compounds?

  • @queazocotal
    @queazocotal Před 17 dny +6

    This video, shortly after watching NurdRage's research into various secondary and tertiary alcohols made me wonder what happens if you replace the ethanol with more exotic alcohols. /me looks at his bottle of tea-tree oil.

    • @stamasd8500
      @stamasd8500 Před 17 dny +4

      *looks at the bottle of linalool, which was obtained as a consequence of the exact same series of videos as above* :)

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +3

      I'll have to give it a shot! I tried methanol instead but it kinda just turned into a weak slime. Didn't think to try longer-chain alcohols

    • @stamasd8500
      @stamasd8500 Před 17 dny +2

      @@integral_chemistry I have a large bottle of geraniol too, might want to give that a try too. Which is again a large chain, unsaturated primary alcohol - as opposed to unsaturated tertiary like linalool.

    • @injectormajor
      @injectormajor Před 16 dny +3

      I have tried propylene glycol and it resulted in more rigid but still flexible material, very bouncy. The reaction time seems the same as with ethanol. Mixture of glycerol and propylene glycol is still curing and I think I made too much of a punk-approach to it with just mix this sh*t at random proportion. I think my goal is to experiment with the number of cross-links and their own length compared to physical prop of cured material. Not that as I’ve asked myself to study that but still)

    • @queazocotal
      @queazocotal Před 16 dny

      @@injectormajor Neat! I wonder if there is a mechanism to make it dry enough to not need the drying step...

  • @tulsatrash
    @tulsatrash Před 17 dny +3

    Not snackable, but whackable.
    Bouncy Ball.

  • @DangerousLab
    @DangerousLab Před 17 dny +2

    Is this another brand of pet pee pads or is it something else? Thinking of getting some for my lab too.

    • @integral_chemistry
      @integral_chemistry  Před 17 dny

      The black ones? Those are actually pads for dental/tattoo work I found on Amazon. They are kinda flimsy compared to the puppy pads but WAY cheaper

    • @DangerousLab
      @DangerousLab Před 17 dny

      @@integral_chemistry Ah I see, I will probably get some during non-filming work as things get messy sometimes.

  • @mattheide2775
    @mattheide2775 Před 17 dny +1

    This looks really cool and all, however, I didn't understand a single concept, yet the bouncy ball kept my attention the entire time. 😅

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +1

      LMAO it was surprisingly fun to play around with. Took me until this video to realized I haven't played with one of these in years

    • @mattheide2775
      @mattheide2775 Před 17 dny

      @@integral_chemistry 1 inch bouncy balls were in gum ball type of vending machine for 25 cents as a kid. Kinda learned geometry and not to bounce it around the house. The one thing I remember is when the ball bounced it would reverse the spin. Like it could grip the surface and put the energy into reverse spin. They were fun to play with my friends and the game was don't look stupid trying to chase the ball. We had a lot of fun chasing around the ball and laughing at each other. Thank you 🙏

  • @andylin1587
    @andylin1587 Před 17 dny

    I may be stupid but how does sodium hydroxide dissolve silicon dioxide which is just glass?

    • @zenongranatnik8370
      @zenongranatnik8370 Před 17 dny

      Strong alkalis just dissolve silicon dioxide creating silicates. Molten NaOH easily dissolves glass and concentrated NaOH solutions can dissolve regular sand under high pressure. If silica is in the form of silica gel it is even easier, you can easily dissolve silica gel cat litter in concentrated sodium hydroxide solution. It's an acid-base reaction, silicon dioxide is a very weak acidic oxide.

    • @eclectichoosier5474
      @eclectichoosier5474 Před 17 dny +1

      NurdRage covered the reaction in his sodium series.
      It's a common problem when working with NaOH, especially at higher temperatures. -- it likes to dissolve your glassware unless you completely eliminate water from your reaction. I've lost a few flasks to it. NurdRage starts his reactions by destroying ALL of the water with sodium metal.

    • @andylin1587
      @andylin1587 Před 16 dny

      @@eclectichoosier5474 Thanks, this was not taught in my chem class :)

  • @mattscanlan5455
    @mattscanlan5455 Před 11 dny +4

    I would really like to see you make addition (platinum) cure silicone. This is the food/medical type.

  • @netram2000
    @netram2000 Před 11 dny +3

    Adding water glass to my diet worked wonders for me. I drink one water glass every hour. Stay sodium silicated, guys!

  • @memberwhen22
    @memberwhen22 Před 17 dny +3

    I read it as Making SIlicon and I was like huh? we are going to journey to a star today

  • @oasntet
    @oasntet Před 17 dny +4

    I just went down a bit of a rabbit hole on the subject of silicone's environmental impact. It's a mixed bag, but not an unmanageable one the way plastic is. It generally breaks down even slower than plastics (I'm sure there are exceptions due to how varied both can be), but that can be a positive for reusable items. It's terrible for disposable items, but ffs we gotta stop with that anyway. But at EOL, it can generally be incinerated safely, unlike plastic, since it mostly produces sand, carbon oxides and water, unlike all of the plasticizers and softeners and adjuncts added to make most plastics useful. Sure, produces carbon dioxide and monoxide, but compared to plastics... Not that it create much energy when incinerated, but the toxic outgassing is less.
    In a future without plastics, maybe we'd use more silicone and have a collection system for it so it goes into incinerators instead of landfills? Or maybe we'd find a recycling system that uses it as a relatively clean source of silica for glassmaking or more silicone?

    • @SianaGearz
      @SianaGearz Před 6 dny

      Plasticisers are a misconception, most plastics you use day to day do not rely on them or don't use any, and in turn with a couple exceptions they can be incinerated completely. PP PE PS PET are the bulk of the plastics used and they can be incinerated completely. There are other trouble additives though, like halogen based fire retardants necessarily used in most PS items and also PVC the polymer per se that's a troublesome one.

  • @notyouraveragegoldenpotato

    Making waterglass is harder than this😂 just mix sodium silicate snd ethanol. Tadaaa. Imma try it. I have a bunch of water glass

  • @hattree
    @hattree Před 17 dny

    Lookup the incredibly weird "Silicones, the answer"

    • @josephpotter5766
      @josephpotter5766 Před 17 dny

      Well.... that was certainly a thing. Well worth the brain damage, i'm sure...

  • @aqua-op
    @aqua-op Před 17 dny +1

    Cool, now try making silicon from scratch

    • @integral_chemistry
      @integral_chemistry  Před 17 dny +2

      Oh christ 😅 honestly a thermite-type reaction could do it, the tough part would be collecting it afterward

    • @zenongranatnik8370
      @zenongranatnik8370 Před 17 dny +1

      ​@@integral_chemistry The longer the cooling time the larger the silicon pieces. You can also recrystallize silicon from molten metals like molten zinc, that way you can extract it from the reaction mixture.

  • @neon_Nomad
    @neon_Nomad Před 15 dny

    Food safe please lmao

  • @jerrysanchez5453
    @jerrysanchez5453 Před 17 dny

    Do it's physical properties make it a non Newtonian solid? Lol

  • @jauld360
    @jauld360 Před 16 dny +1

    Cat litter to silicone would make a catchy title.

  • @charlesurrea1451
    @charlesurrea1451 Před 15 dny +1

    This is when you wish you had a lab Rolling Mill

  • @timobatana6705
    @timobatana6705 Před 16 dny

    To think that City women are made up of something that you can mix in a beaker very quickly......

  • @Tyresio12
    @Tyresio12 Před 16 dny

    I don't think your explanation and the reaction given are true.
    First, any crosslinking would require a molecule with at least two functional groups, and ethanol has only one.
    Second, your reaction has oxygen as a product. Ask yourself - is really any gas produced? Keep in mind that the stoichiometry you've provided dictates that for each mole of ethanol reacting (ca. 50 ml) you'd get over 20 liters of oxygen. That's quite an off-gas, I'd say.

  • @Djoodibooti
    @Djoodibooti Před 12 dny

    Finally one step closer to making my very own home made from scratch silicone breast implants. They're gonna be FUCKIN HUGE.

  • @williambradley611
    @williambradley611 Před 17 dny +2

    Like this comment

  • @Dan-vq4pz
    @Dan-vq4pz Před 14 dny

    Are you formerly The Gayest Person on CZcams?

    • @Dan-vq4pz
      @Dan-vq4pz Před 14 dny

      If so, I really like your thermite series

  • @samhaine6804
    @samhaine6804 Před 12 dny

    nice video dude but... really? throwing your dumb chemistry experiment (what is essentially chemical waste) around the street in the dark and losing it in your neighbours gardens? wildly irresponsible and possibly even criminal. dislike 👎

    • @integral_chemistry
      @integral_chemistry  Před 8 dny

      You sound fun.. Its a silicate polymer, no different and honestly safer/more biodegradable than one you'd purchase at a store. I found the one I initially lost (and included footage to show I found it), and I consulted the two neighbors down before I started which honestly was a courtesy and completely unnecessary. You must completely misunderstand fundamental chemistry because to imply throwing a safer version of a rubber ball down the street to be criminal is absurd.

  • @bnarit
    @bnarit Před 17 dny +1

    the Best Synthesis Clip ever,.....

  • @Axman6
    @Axman6 Před 16 dny

    I’m just here for the software optimisation content 🥲