28. Transition Metals: Crystal Field Theory Part I

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  • čas přidán 20. 08. 2024
  • MIT 5.111 Principles of Chemical Science, Fall 2014
    View the complete course: ocw.mit.edu/5-...
    Instructor: Catherine Drennan
    Crystal field theory was developed to explain the special features of transition metal complexes, including their beautiful colors and their magnetic properties. In part I of this topic, we consider d-block coordination complexes that have octahedral geometry, and see whether we can change the color of a paper flower dipped in an octahedral cobalt chloride complex just by adding water.
    License: Creative Commons BY-NC-SA
    More information at ocw.mit.edu/terms
    More courses at ocw.mit.edu

Komentáře • 105

  • @Hiitsmyhandle
    @Hiitsmyhandle Před 3 lety +75

    I had to momentarily pause the video midway to say, I think this lecture, and many in the series have saved my chemistry degree. My teachers are just useless at explaining this content in tutorials and in the written content it's even worse! Why do uni's insist on over-complicating things to the point where you become disheartened? I truly thought I was too dumb to comprehend this topic, now I'm just irritated that it took me so long to find a really good explanation, but I'm also really motivated about the rest of the course. Thank you, Catherine.

    • @zacharyfalkowski
      @zacharyfalkowski Před 2 lety

      Cal professors love to overcomplicate chem

    • @moksokha2007
      @moksokha2007 Před 2 lety

      4
      4

    • @moksokha2007
      @moksokha2007 Před 2 lety

      7

    • @stauffap
      @stauffap Před 2 lety +2

      Yeah, that's often the key to understanding any topic. For a person with normal intelligence there's not topic that can't be understood. So if you don't understand something it's usually just not explained very well in terms of the knowledge your already posess.
      So you just need to find people, books, websites etc. that explain in a way that you understand.

  • @morrisdweck32
    @morrisdweck32 Před 7 lety +72

    This video is extremely clear and includes example questions to check your understanding periodically. Highly recommend this video to all those either looking to learn or review this topic

  • @anp9929
    @anp9929 Před 3 lety +5

    this video basically exposed the fact that other chem professors dont know what tf theyre doing. this is how you teach a class and demonstrate abstract theories. not a single instance of reading off the slide, so 100 catherine i love u

  • @lettuceface
    @lettuceface Před 6 lety +59

    BLESS THIS WOMAN, ive been looking everywhere for proper explanation of this topic, finally found it, thank you :)

  • @damongeo840
    @damongeo840 Před 5 lety +9

    Well in my University it takes one quick and condensed lecture and you go home with barely the title in your mind - "It is not needed to know these stuff for any job - only for "teaching" it to students to pass the examination". Loved the lecture very much, thank you for sharing!

  • @userismad001
    @userismad001 Před 3 lety +7

    I saw one of her classes from 11 years back MIT just now and this one followed... still the quality of education being imparted is priceless.. thank you Maam.

  • @kp74952
    @kp74952 Před 5 lety +4

    Wow this is so much easier to understand than my chem lectures...plus a lot more fun to listen to...wish teachers could all be this clear and interesting!

  • @seanchang878
    @seanchang878 Před 5 lety +2

    She amazing teacher and always uses humor way to fully explain the difficult chemistry rules

  • @campbellogenrwot5666
    @campbellogenrwot5666 Před 2 lety

    the best chemistry teacher so far, thank God i came across this masterpiece

  • @mdsaim9779
    @mdsaim9779 Před 2 lety

    Only these lectures can give the real feelings of chemistry

  • @amadeusakreveusmusic3356

    This lady is a breath of fresh air in the dullest education institution, ie university.

  • @bian9347
    @bian9347 Před 6 měsíci

    Wow, that woman and the way she teaches is amazing 👌👌👌

  • @lolozzz8864
    @lolozzz8864 Před 4 lety +1

    This is clearly the difference between an MIT class and a class from my University (im from Uruguay and I understood this just perfectly!) thanks

  • @chanky1000
    @chanky1000 Před 5 měsíci

    This is so beautiful!!! Chemistry is so much fun and interesting!

  • @dr.abdelmounaimchetoui

    I would like to say that this lecture is stunning and amazing. I really enjoyed every part of the lecture, it was clear, the examples are just great. Thank you Pr. Drennan. The fruit of Pr. Ludwig is in front of you.

  • @mohsentamtaji9130
    @mohsentamtaji9130 Před 2 lety +1

    Really thanks for your clear explanations. I learned a lot to explain my quantum mechanics calculation results.

  • @sammyhunnid
    @sammyhunnid Před 2 lety

    Most insightful video on Crystal Field Splitting Energy/ Possible applications. Merci Beaucoup.

  • @chancheng6893
    @chancheng6893 Před 2 lety

    This is so good and clearly understand than my university lecture, was searching this topic to clear my mind before exams,
    thank you

  • @Malikin
    @Malikin Před 2 lety

    All it takes is willing interestedness of a teacher to teach

  • @anonymousraider8568
    @anonymousraider8568 Před 5 lety +9

    And here I have to deal with this in better details right in class 12. #StrugglesInCBSE

  • @kameshmishra6306
    @kameshmishra6306 Před 5 lety +2

    I love this type lectures

  • @delq
    @delq Před 4 lety +5

    This was awesome - loved the teaching , clarity and 16:36 was the best

  • @MohamedMarawan403
    @MohamedMarawan403 Před rokem +1

    Thank you for this Lecture 🙂
    It is very fantastic.
    I wish I will attend in this university in The Nearest Future .

  • @iskalasrinivas5640
    @iskalasrinivas5640 Před 10 měsíci +1

    Thanks for amazing explanation this really helped my research 🎉

  • @zack_120
    @zack_120 Před rokem

    15:20- "energy conserved" making the understanding of the splitting energy easier 👍
    39:05- so, that means PE

  • @p.s.design4338
    @p.s.design4338 Před 7 lety +5

    excellent lecture...

  • @ahmedhegazy8236
    @ahmedhegazy8236 Před 7 lety +1

    we wonna thank mit for their magic justification and we need courses about teaching

  • @rampalchauhan7819
    @rampalchauhan7819 Před 3 lety +1

    Thanks

  • @eshfaq7564
    @eshfaq7564 Před 3 lety

    Mam just awesome.you have cleared my confusion. Love you from Bangladesh 🇧🇩🇧🇩
    Adamjee Cantonment College

  • @rkkncole9463
    @rkkncole9463 Před 6 lety +2

    You are great at what you do! Great teacher!

  • @ItalianCooking-fm7ut
    @ItalianCooking-fm7ut Před 2 lety

    Such an impressive lecturer!

  • @MuntazirMahdi10
    @MuntazirMahdi10 Před 3 lety

    One of my favorite Madam,

  • @sajidhussain3
    @sajidhussain3 Před 6 lety +2

    Extremely understandable. Thanks

  • @user-cp3qm2dt6k
    @user-cp3qm2dt6k Před 8 měsíci

    thanks for the lesson I've learnt a lot, i wish that one day i will come to MIT🙂

  • @lemonguet5448
    @lemonguet5448 Před 2 měsíci

    Excellent lecture!! But I had to pause for a while 'cause of that 'ah' in 16:35 lol

  • @harshraj34512
    @harshraj34512 Před 2 lety

    Completely understand each and every topics thanks 🙏

  • @fouzhanda7649
    @fouzhanda7649 Před rokem

    you are amazing i wish you were our professor

  • @jlafa622
    @jlafa622 Před 5 lety +1

    Wow, this all makes sense now! Thanks so much!

  • @someone8987
    @someone8987 Před 5 lety

    Great .....Really Incredible....I wish to have such awesome classes..

  • @ucf_zn
    @ucf_zn Před rokem

    "من علمني حرفاً كنت له عبداً"

  • @saptantoputra7937
    @saptantoputra7937 Před 3 lety

    Simple theory can explained alot

  • @Fun_in_Germary
    @Fun_in_Germary Před 3 lety

    Loved this excellent teaching.

  • @jaeek0404
    @jaeek0404 Před 2 lety

    Thank you Prof.!

  • @ottolehikoinen6193
    @ottolehikoinen6193 Před 3 lety

    Thanks for the lecture, you made me seek out my copy of Jolly's modern inorganic chemistry book. It looks like I've actually read it :-)

  • @dcfan7501
    @dcfan7501 Před 3 lety

    Her T shirts are just ❤.

  • @nikiarde
    @nikiarde Před 6 lety +2

    THANK YOU SO MUCH

  • @damongeo840
    @damongeo840 Před 4 lety

    Shouldn't the deexcitation of electrons produce back the green color (500 nm) while all the other colors in the visible range being absorbed for incomplete excitation of the electrons? You know, like the atomic absorption spectroscopy (AAS) principle. 50:00

  • @taraabed8746
    @taraabed8746 Před 4 lety

    She is awesome

  • @Leo-zp3si
    @Leo-zp3si Před rokem

    I loved this class

  • @Princesaalexandrine
    @Princesaalexandrine Před 6 lety

    Amazing clarity

  • @yatint9665
    @yatint9665 Před 6 lety +2

    Very well explained 👍

  • @priyanshusharma2310
    @priyanshusharma2310 Před 3 lety

    The topic is so well explained :)

  • @srishtiparihar960
    @srishtiparihar960 Před 7 lety +1

    awesome lectures

  • @davidwilkie9551
    @davidwilkie9551 Před 3 lety

    In Totality of vertices and vortices Singularity Superspin In-form-ation in/of Eternity-now Interval superposition identification of elemental e-Pi-i sync-duration resonances.., WYSIWYG here-now-forever including these Crystallisation positioning properties of +/-Inflation orbital bubble-modes as shown. The Universal axial-tangential sync-duration balance Singularity, e-Pi-i here-now-forever phenomenonological Timing-spacing is shaping in Perspective of logarithmic numberness dominance of energy levels. Ie, Chemistry aka the instantaneous focus of Temporal QM In-form-ation sequences in the 1-0 probability bonding dominance Interval.

  • @ttolshipping5457
    @ttolshipping5457 Před měsícem +1

    oh MY GOD THIS IS FREE????!!!!?

  • @geniegenie2453
    @geniegenie2453 Před rokem

    I'm sure it's a stupid question, but octahedral means 6 bonds and we have FIVE d orbitals. So where exactly are the electrons from the ligand going?

  • @educhick9967
    @educhick9967 Před 4 lety

    Thanks ma'am

  • @pauloeduardo4916
    @pauloeduardo4916 Před 4 lety +1

    Hi, everybody. Why, at the minute 20:34, she got 5 for the d count? From where the 8 cames? Thank you.

    • @ruvi2754
      @ruvi2754 Před 4 lety

      hello!
      if u count in the periodic table the number of groups from the metal (ie grp 1) until Fe, Fe would be under 'group 8'.
      to find the count, u take the group no (so 8) - the oxidation number, 3(u can ignore the +/- sign) which gives u 5.

  • @shampapaul102
    @shampapaul102 Před 5 lety

    Very Informative video , Thanks .

  • @HuHuxLoops
    @HuHuxLoops Před 5 lety

    Amazing lecturer.

  • @SaraAhmed-se9xj
    @SaraAhmed-se9xj Před 5 lety

    a lot of thinks from my heart doctor💜💜

  • @shashiraj6998
    @shashiraj6998 Před 3 lety +2

    We study these in High School in India. 😁

  • @siliconrod3248
    @siliconrod3248 Před rokem

    Thank you soooooooo...(o x 42) much!

  • @piyushdaigavhane3488
    @piyushdaigavhane3488 Před 3 lety +1

    Lol, everybody in comment section seems to be from university, I am in 12th grade, watching this

  • @cavelinguam6444
    @cavelinguam6444 Před 5 lety

    Awesome thanks

  • @ibrahimnana-balqiz7395

    Thanks alot

  • @big3ye378
    @big3ye378 Před 4 lety

    How does the 6th ligand coordinate? Does it fill an empty p orbital?

  • @malikah14otrew
    @malikah14otrew Před 4 lety

    Okay but seriously thank you 🙏🏿🙏🏿🙏🏿 My prof can't teach whatsoever 😭

  • @headshitmemor3019
    @headshitmemor3019 Před 3 lety +1

    Does MIT not have the culture of asking doubts by raising hands while the teacher has paused, or is everyone smart enough to understand it completely?

    • @mitocw
      @mitocw  Před 3 lety +3

      One thing that many of our course videos are missing are the recitations. Many courses have recitation sessions where students are welcome to ask questions on anything they are confused on. For example, 5.111 recitations met 2 times per week for 1 hour per session; 26 sessions total; mandatory attendance. For more information, visit ocw.mit.edu/5-111F14. Best wishes on your studies!

    • @headshitmemor3019
      @headshitmemor3019 Před 3 lety +1

      @@mitocw Thank You Very Much! It really is helpful! Best Wishes to everyone too!

  • @amanbhavsar2097
    @amanbhavsar2097 Před 3 lety

    And there is me... studying more deeply than them in class 12 for jee advanced 😭😭😭😭

  • @plukvanderberg7475
    @plukvanderberg7475 Před 5 lety

    THANK YOUUUUUUUUUU

  • @chakradarreddy7079
    @chakradarreddy7079 Před 5 lety

    IN CFSE the value is 0 in the case of fe(h2o)6 ,so why would they split into two different categories of energies as t2g and eg

    • @pheonixnova4383
      @pheonixnova4383 Před 5 lety

      Chakradar reddy -100 +100 =0

    • @watsoncrick6071
      @watsoncrick6071 Před 2 lety

      stabilizing energy is different from splitting energy. You need splitting energy to split those d orbitals. The fact that CFSE is 0 is just attributed to the relative stability of the t2g and eg.

  • @madhavsharma6845
    @madhavsharma6845 Před 2 lety

    where can i get the notes mentioned in the lecture if its possible?

  • @Meraki.chemsci
    @Meraki.chemsci Před 3 lety

    See this link 38 seconds only for chemistry

  • @moosehead4497
    @moosehead4497 Před 2 lety

    "octahedral crystal field splitting energy" when you could just say "delta"

    • @MetalikeV
      @MetalikeV Před 2 lety

      Many energy differences such as those between orbitals, states, etc. are called "delta". This is a course that is defining this particular "delta" for the first time and it makes sense to say "octahedral crystal field splitting energy" multiple times. This isn't a graduate level inorganic course.

  • @abhishekkumarranjan9162

    Somebody notice her t shirt it's pretty cool

  • @reshukumar1229
    @reshukumar1229 Před 4 lety

    Where do I find the other parts?

    • @mitocw
      @mitocw  Před 4 lety +1

      View the course on MIT OpenCourseWare for all the parts at: ocw.mit.edu/5-111F14. Best wishes on your studies!

    • @reshukumar1229
      @reshukumar1229 Před 4 lety

      @@mitocw Thank You very much!

  • @avijitdey992
    @avijitdey992 Před 4 lety +2

    I tell bad chemistry jokes because all the good jokes *Ar*

  • @mulekebede3707
    @mulekebede3707 Před 5 lety

    👌

  • @yousefmohsen6287
    @yousefmohsen6287 Před rokem

    رهيب❤️🥹😍

  • @SameerKumar-xy8ky
    @SameerKumar-xy8ky Před 4 lety

    Notice her t shirt.

  • @kendrafuller5821
    @kendrafuller5821 Před 4 lety

    She reminds me of velma once she had to retire from the mystery gang

  • @oneinabillion654
    @oneinabillion654 Před 5 lety

    A level student here hahahaa