Law of crystal symmetry | Solid State | Physical Chemistry
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“Every crystal shows various types of symmetry.”
“All crystals of the same substance possess the same elements of symmetry.”
When a crystal is rotated about its axis, it shows the same appearance it is known as crystal symmetry.
Various types of symmetry in a crystal is known as elements of symmetry.
Centre of Symmetry:It is defined as an imaginary point within the crystal such that any line passing through this point intersects the opposite face of the crystal at equal distances.
In other words, any line drawn through this point will intersect surface at equal distance in both the directions.
Plane of Symmetry:It is an imaginary plane which divides the crystal into two equal parts such that one is the mirror image of the other.
For example, regular cubic structure can have 9 planes of symmetry. Three planes of symmetry are parallel to the cube faces and six diagonal planes are passing through opposite cube edges.
Axis of Symmetry:Axis of symmetry is a line about which the crystal may be rotated such that it presents the same appearance more than once during the complete revolution through 360o.
If a crystal presents the same appearance ’n’ times in one complete revolution, the axis is said to be ’n’ fold symmetry.
E.g. the cubic crystal of NaCl has 13 axes of symmetry out of which 4 are threefold, 3 are fourfold and 6 are twofold.
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This has helped me understand symmetry much better, thank you
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This guy is confused in between group symmetry and crystal symmetry and its elements
Why a crystal can't have a 5 fold symmetry
there is a long proof for that using the rotation matrix , but short answer is that "n" fold axis can happen when [ 1+ 2 cos(2*pi/n) ] is integer. that's why we can't have n=5,7,...
@@hebahthephysicist9349 yeah I saw that later too in KL Kapoor's book too
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