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Physical Chemistry
United States
Registrace 6. 04. 2020
Short videos covering the full range of topics in an undergraduate physical chemistry course, in a "Boltzmann-first" order.
Start here: czcams.com/video/OVVcePiou2I/video.html, then follow the link at the end of each video to work through the whole course. There are also playlists for each section of the course:
Introduction
Probability
Entropy
Optimization
Boltzmann
Quantum Mechanics
One-Dimensional Particle in a Box
Postulates of Quantum Mechanics
Partition Function
3D Particle in a Box
Ideal Gas
Kinetic Thy of Gases
Gases
Thermodynamic State
Rigid Rotor
Harmonic Oscillator
Diatomic Molecules
Spectroscopy
Solids
Symmetry
Spontaneity
Free Energy
Thermo. Relationships
Phase Equilibria
Solutions
Electrolytic Solutions
Hydrogen Atom
Many-Electron Atoms
Nuclei
Chemical Equilibrium
Surfaces
Lasers
Most can stand on their own, and have links back to earlier material if you need a refresher, so feel free to jump in where you like.
Happy PChem-ing!
email: lytica.pchem[at]gmail.com
Start here: czcams.com/video/OVVcePiou2I/video.html, then follow the link at the end of each video to work through the whole course. There are also playlists for each section of the course:
Introduction
Probability
Entropy
Optimization
Boltzmann
Quantum Mechanics
One-Dimensional Particle in a Box
Postulates of Quantum Mechanics
Partition Function
3D Particle in a Box
Ideal Gas
Kinetic Thy of Gases
Gases
Thermodynamic State
Rigid Rotor
Harmonic Oscillator
Diatomic Molecules
Spectroscopy
Solids
Symmetry
Spontaneity
Free Energy
Thermo. Relationships
Phase Equilibria
Solutions
Electrolytic Solutions
Hydrogen Atom
Many-Electron Atoms
Nuclei
Chemical Equilibrium
Surfaces
Lasers
Most can stand on their own, and have links back to earlier material if you need a refresher, so feel free to jump in where you like.
Happy PChem-ing!
email: lytica.pchem[at]gmail.com
Adiabatic Flame Temperature
The enthalpy of combusion can be used to estimate the temperature at which a flame will burn.
zhlédnutí: 16 252
Video
Lattice Models (Energy Transfer)
zhlédnutí 4KPřed 2 lety
Lattice models can be used not only for the position of molecules, but also for their energies.
Heat Pump
zhlédnutí 3,1KPřed 2 lety
A heat pump is the opposite of a heat engine. Rather than obtaining useful work as heat flows "downhill" from hot to cold, a heat pump uses work as an input in order to pump heat "uphill" from cold to hot.
Carnot Theorem
zhlédnutí 6KPřed 2 lety
The Carnot Theorem states that the efficiency of any reversible heat engine operating between a pair of temperatures is the same. It depends only on the two temperatures, and not on the type of heat engine, or the substances involved.
Heat Engine
zhlédnutí 6KPřed 2 lety
A heat engine makes use of the natural tendency of heat to flow from hot to cold, and converts some of that heat to work. The efficiency of a heat engine describes what fraction of that input heat can be converted to work.
Carnot Cycle
zhlédnutí 24KPřed 3 lety
A sequence of isothermal and adabatic expansions and compressions of an ideal gas, called the Carnot Cycle, provides a way to turn heat into work.
Particle on a Ring
zhlédnutí 10KPřed 3 lety
The 1D particle-in-a-box model describes a particle confined to move along a line. When the particle is instead confined to a circle, its behavior is different, and can be described with the particle-on-a-ring model.
Air Pressure at Altitude
zhlédnutí 7KPřed 3 lety
The Boltzmann distribution can be used to calculate how the air pressure drops with altitude.
Introduction
zhlédnutí 15KPřed 3 lety
This channel contains short videos covering the entire scope of a two-semester undergraduate physical chemistry course. Here are my tips for how to learn physical chemistry by watching videos, along with some discussion of the features of these particular videos.
What is Physical Chemistry?
zhlédnutí 36KPřed 3 lety
What topics fall under the category of physical chemistry, and what do they have in common?
Lightboard - Behind the Scenes
zhlédnutí 16KPřed 3 lety
These videos are recorded using a lightboard. The image is digitally reversed so that you can read what I'm writing on the back side of the glass.
Boltzmann-First PChem
zhlédnutí 6KPřed 3 lety
The topics in physical chemistry are fairly standard, but the order in which they are presented varies a lot from one course or textbook to another. With a "Boltzmann-first" approach, paying a little extra attention to the Boltzmann distribution at the start allows many other topics to be introduced in a very natural way.
He-Ne Laser
zhlédnutí 8KPřed 3 lety
A helium-neon laser takes advantage of the similarity in energy between an excited state of He gas and a different state for Ne gas. The He is pumped into the excited state, and the lasing transition occurs in the Ne, emitting red light of 633 nm.
Three-State Laser
zhlédnutí 2,2KPřed 3 lety
The population inversion needed for a laser can't be achieved with just two electronic states. But with three states, the system can be pumped up to an upper state, in order to maintain a population inversion relative to an intermediate state.
Lasers (Basics)
zhlédnutí 4,2KPřed 3 lety
A laser differs from an ordinary light source: the photons in a laser light source are monochromatic, collimated, and coherent.
Langmuir Adsorption - Statistical Mechanics
zhlédnutí 7KPřed 3 lety
Langmuir Adsorption - Statistical Mechanics
Temperature Dependence of the Equilibrium Constant
zhlédnutí 8KPřed 3 lety
Temperature Dependence of the Equilibrium Constant
Best teacher ever
Mannnn! A gem a I have found. How deeply he felt the topics and explained is such a joy learn !
my teacher gave notes that complicated this simple stuff into such complex equations with no explanation. with just an analogy you brought this into limelight. much thanks to you sir!
Thank you! My professor went on and on about how these were derived, but never really explained what the adjustments were for or why they were important. This is great, I really appreciate your videos!
Sir thank you for the videos i am an indian student aiming for higher studies and physical chemistry is where i would love to continue my journey .....you have provided us a very intuitive and logical course in short and concise videos...how i wish more people knew the beauty of this course🤝
Rodriguez Joseph Thomas Donna Robinson Nancy
Hi! Thanks for the videos, they're a great resource! I will be teaching PChem soon. Question: The work formula was derived using the definition of internal energy and microscopic pressure, both describing the system. So why is the macroscopic pressure in the general formula all of a sudden the external pressure? I am struggeling to understand where in the derivation the reversibility was assumed.
Thank you for this great video it explains very clearly the concept
Their is difference between gas and vapour but you use them alternatively 😢
🎉any jee aspirants any jee aspirants
Helped me a lot, congrats for the job
Good for jee advanced
But molar mass of benezne is 78??
Thank you so much for this video! My prof essentially hand-waved this topic and left us to study it on our own, so this was such a big help.
wow, are you writing backwards on the "blackboard glass"?
Thankyou so much.
this is a perfect video that helped me twice understanding the joule-thomson effect! thank you very muchh
Is he writing backwards or was the video flipped?
4:45 i found an error with the labeling of the states, the ground state is n=0 so the 5th is actually the fourth and the sixth the 5th that way the number of nodes are equal to n
Why is the external and internal pressure equal whenever you do it slowly? Wouldn't the internal pressure be greater than 1 all the way till the end?
Oh it's pressure not from the Pext but from you holding it there and slowly allowing it to expand huh
thank you
Thank you so much sir !
you also studying this rn lol, same
@@HydraWerewolf haha
Dr Stuart is excellent instructor.
Thank you very much! I can now understand how that actually works! You actually deserve much more subs and views than mere thousands! Btw a little fun fact: you didn't say "Joule Thomson Effect" in the whole video; anyways, it was interesting! Thanks again!
7:12 If the boundary condition is that our wavefunction psi(x,y,z) = X(x)Y(y)Z(z) = 0 when x = 0 or a, y = 0 or a, z = 0 or a, why do we choose to take X(x) = 0 when x = 0 or a, Y(y) = 0 when y = 0 or a and Z(z) = 0 when z = 0 ot a as our boundary conditions for the three Ordinary differential equations? We don't have to take these to satisfy the above boundary condition for psi(x,y,z)? For example, to satisfy psi(x,y,z) = 0, couldn't we have X(x) = a/2 when x = 0 for the first ODE, since Y(y) or Z(z) could still be zero instead meaning psi is zero. Or does the fact that X, Y and Z are independent functions preclude this.
I can't thank you enough. You've been helping me in my review for my licensure exam. Your explainations are very clear.
Thank you so much for this concise explanation.
Perfect explanation❤
As a biochemistry scientist, I’ve used this Debye-Huckel formula along side Henderson-Hasselbach equation to prove a certain mobile phase solution recipe was wrong in the lab I work at and how the pH range was not inline with the method stated.
another fantastic video thanks
thank you for amazing upload it is much appreciated.💯
thank you for the upload you actually made this make sense in my head.
Entropy is always positive, right?
Rigid rotator derivation send link sir
How exactly does changing the limits of integration equate to throwing away one of the bars on the low end side fo the integral? My intuition tells me that by moving the bound to zero, you would essentially add in a bar of e^-0. Thank you so much for this series!
Thank you so much. This was really helpful
how can you explain macromolecules transitions? (lipids, proteins and dna)
very insightful. thank you prof.
I have a doubt
i hate physical chemistry
Med student here! I remember the Shroedinger equation but we spent more time solving hydrogen and other calculus for energy states than extrapolating key concepts like thus, bravo!
Is Q here the molecular partition function or the canonical partition function?
There’s is an inproper rotation S for the Q right. If you rotate 180 degrees through the axis pointing to you out of the screen (the dot in the middle of the Q being the tip of the arrow pointing towards you) the little line of the Q is in the top left part of the circkle inverting through the center brings it back to the right bottom. 4:27
I learned from other class that this equation can lead to Le Chatelier's principle about the change of T, but I still can't understand how.
Not sure if this answers your question but this equation basically says that the rate of change of free energy, with respect to temperature, is negative with respect to temperature squared, not sure how this can be converted to systems in equilibrium but so long as the system is closed, this negative proportional relationship means that changing the temperature favours the reaction that reverses the direction of temperature change
cool
From India, helped a lot for school thank you ❤❤
life of jee Students like us! btw which class r u in?
Thank you sir !
I would pre-heat the oxygen and fuel molecules electromagnetically. Then record the 3D volumetric temperature distribution, tracking flow of reactants. To start. And find the temperature dependent heat capacities data or models. To start. Calibrate and optimized the linked models. Track spectroscopic IR, VIS, thermal, UV, whatever is available. Share the results. Richard Collins, The Internet Foundation
Thanks for these videos. Although it is extremely unlikely that you are generating much ad revenue from my views, these videos are making a huge impact on my educational success. I'm reviewing my textbook for next semester; it might as well be Egyptian hieroglyphics without your help.
holy sh+t that was the best explaination of exact differentiation application. Explaination + & - was very helpful