Physical Chemistry
Physical Chemistry
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Adiabatic Flame Temperature
The enthalpy of combusion can be used to estimate the temperature at which a flame will burn.
zhlédnutí: 16 252

Video

Lattice Models (Energy Transfer)
zhlédnutí 4KPřed 2 lety
Lattice models can be used not only for the position of molecules, but also for their energies.
Heat Pump
zhlédnutí 3,1KPřed 2 lety
A heat pump is the opposite of a heat engine. Rather than obtaining useful work as heat flows "downhill" from hot to cold, a heat pump uses work as an input in order to pump heat "uphill" from cold to hot.
Carnot Theorem
zhlédnutí 6KPřed 2 lety
The Carnot Theorem states that the efficiency of any reversible heat engine operating between a pair of temperatures is the same. It depends only on the two temperatures, and not on the type of heat engine, or the substances involved.
Heat Engine
zhlédnutí 6KPřed 2 lety
A heat engine makes use of the natural tendency of heat to flow from hot to cold, and converts some of that heat to work. The efficiency of a heat engine describes what fraction of that input heat can be converted to work.
Carnot Cycle
zhlédnutí 24KPřed 3 lety
A sequence of isothermal and adabatic expansions and compressions of an ideal gas, called the Carnot Cycle, provides a way to turn heat into work.
Particle on a Ring
zhlédnutí 10KPřed 3 lety
The 1D particle-in-a-box model describes a particle confined to move along a line. When the particle is instead confined to a circle, its behavior is different, and can be described with the particle-on-a-ring model.
Air Pressure at Altitude
zhlédnutí 7KPřed 3 lety
The Boltzmann distribution can be used to calculate how the air pressure drops with altitude.
Introduction
zhlédnutí 15KPřed 3 lety
This channel contains short videos covering the entire scope of a two-semester undergraduate physical chemistry course. Here are my tips for how to learn physical chemistry by watching videos, along with some discussion of the features of these particular videos.
What is Physical Chemistry?
zhlédnutí 36KPřed 3 lety
What topics fall under the category of physical chemistry, and what do they have in common?
Lightboard - Behind the Scenes
zhlédnutí 16KPřed 3 lety
These videos are recorded using a lightboard. The image is digitally reversed so that you can read what I'm writing on the back side of the glass.
Boltzmann-First PChem
zhlédnutí 6KPřed 3 lety
The topics in physical chemistry are fairly standard, but the order in which they are presented varies a lot from one course or textbook to another. With a "Boltzmann-first" approach, paying a little extra attention to the Boltzmann distribution at the start allows many other topics to be introduced in a very natural way.
He-Ne Laser
zhlédnutí 8KPřed 3 lety
A helium-neon laser takes advantage of the similarity in energy between an excited state of He gas and a different state for Ne gas. The He is pumped into the excited state, and the lasing transition occurs in the Ne, emitting red light of 633 nm.
Three-State Laser
zhlédnutí 2,2KPřed 3 lety
The population inversion needed for a laser can't be achieved with just two electronic states. But with three states, the system can be pumped up to an upper state, in order to maintain a population inversion relative to an intermediate state.
Lasers (Basics)
zhlédnutí 4,2KPřed 3 lety
A laser differs from an ordinary light source: the photons in a laser light source are monochromatic, collimated, and coherent.
BET Isotherm - Linear Form
zhlédnutí 5KPřed 3 lety
BET Isotherm - Linear Form
BET Isotherm - Discussion
zhlédnutí 4,3KPřed 3 lety
BET Isotherm - Discussion
BET Adsorption Isotherm
zhlédnutí 9KPřed 3 lety
BET Adsorption Isotherm
BET Adsorption Model
zhlédnutí 8KPřed 3 lety
BET Adsorption Model
Langmuir Adsorption - Limitations
zhlédnutí 4KPřed 3 lety
Langmuir Adsorption - Limitations
Langmuir Isotherm - Adsorbed Volume
zhlédnutí 8KPřed 3 lety
Langmuir Isotherm - Adsorbed Volume
Langmuir Isotherm - Linear Form
zhlédnutí 22KPřed 3 lety
Langmuir Isotherm - Linear Form
Langmuir Isotherm - Kinetics
zhlédnutí 10KPřed 3 lety
Langmuir Isotherm - Kinetics
Langmuir Isotherm - Thermodynamics
zhlédnutí 6KPřed 3 lety
Langmuir Isotherm - Thermodynamics
Langmuir Isotherm
zhlédnutí 9KPřed 3 lety
Langmuir Isotherm
Langmuir Adsorption - Statistical Mechanics
zhlédnutí 7KPřed 3 lety
Langmuir Adsorption - Statistical Mechanics
Langmuir Adsorption - Model
zhlédnutí 18KPřed 3 lety
Langmuir Adsorption - Model
Adsorption
zhlédnutí 30KPřed 3 lety
Adsorption
Temperature Dependence of the Equilibrium Constant
zhlédnutí 8KPřed 3 lety
Temperature Dependence of the Equilibrium Constant
van't Hoff Equation
zhlédnutí 15KPřed 3 lety
van't Hoff Equation

Komentáře

  • @EmadShamma
    @EmadShamma Před 12 hodinami

    Best teacher ever

  • @rupjit27
    @rupjit27 Před 22 hodinami

    Mannnn! A gem a I have found. How deeply he felt the topics and explained is such a joy learn !

  • @karikalan7867
    @karikalan7867 Před dnem

    my teacher gave notes that complicated this simple stuff into such complex equations with no explanation. with just an analogy you brought this into limelight. much thanks to you sir!

  • @ninaciriello8346
    @ninaciriello8346 Před 2 dny

    Thank you! My professor went on and on about how these were derived, but never really explained what the adjustments were for or why they were important. This is great, I really appreciate your videos!

  • @kevinlalhruaitluanga8933

    Sir thank you for the videos i am an indian student aiming for higher studies and physical chemistry is where i would love to continue my journey .....you have provided us a very intuitive and logical course in short and concise videos...how i wish more people knew the beauty of this course🤝

  • @MarthaHenry-r6w
    @MarthaHenry-r6w Před 4 dny

    Rodriguez Joseph Thomas Donna Robinson Nancy

  • @marqvorsen
    @marqvorsen Před 8 dny

    Hi! Thanks for the videos, they're a great resource! I will be teaching PChem soon. Question: The work formula was derived using the definition of internal energy and microscopic pressure, both describing the system. So why is the macroscopic pressure in the general formula all of a sudden the external pressure? I am struggeling to understand where in the derivation the reversibility was assumed.

  • @MáximoMarrese
    @MáximoMarrese Před 8 dny

    Thank you for this great video it explains very clearly the concept

  • @Dheeraj5373
    @Dheeraj5373 Před 8 dny

    Their is difference between gas and vapour but you use them alternatively 😢

  • @KazeNokorai
    @KazeNokorai Před 8 dny

    🎉any jee aspirants any jee aspirants

  • @daviantonio5313
    @daviantonio5313 Před 8 dny

    Helped me a lot, congrats for the job

  • @KazeNokorai
    @KazeNokorai Před 9 dny

    Good for jee advanced

  • @jesugbogoenis
    @jesugbogoenis Před 15 dny

    But molar mass of benezne is 78??

  • @under_the_night_sky5380

    Thank you so much for this video! My prof essentially hand-waved this topic and left us to study it on our own, so this was such a big help.

  • @Bisnard0
    @Bisnard0 Před 16 dny

    wow, are you writing backwards on the "blackboard glass"?

  • @sanika3280
    @sanika3280 Před 20 dny

    Thankyou so much.

  • @selin3780
    @selin3780 Před 22 dny

    this is a perfect video that helped me twice understanding the joule-thomson effect! thank you very muchh

  • @Friedrice12121
    @Friedrice12121 Před 22 dny

    Is he writing backwards or was the video flipped?

  • @jimpanse1638
    @jimpanse1638 Před 22 dny

    4:45 i found an error with the labeling of the states, the ground state is n=0 so the 5th is actually the fourth and the sixth the 5th that way the number of nodes are equal to n

  • @jackobrien9864
    @jackobrien9864 Před 23 dny

    Why is the external and internal pressure equal whenever you do it slowly? Wouldn't the internal pressure be greater than 1 all the way till the end?

    • @jackobrien9864
      @jackobrien9864 Před 23 dny

      Oh it's pressure not from the Pext but from you holding it there and slowly allowing it to expand huh

  • @HydraWerewolf
    @HydraWerewolf Před 23 dny

    thank you

  • @user-ej5ii7fe4p
    @user-ej5ii7fe4p Před 25 dny

    Thank you so much sir !

  • @aussiedog5221
    @aussiedog5221 Před 26 dny

    Dr Stuart is excellent instructor.

  • @Suraj0l
    @Suraj0l Před 29 dny

    Thank you very much! I can now understand how that actually works! You actually deserve much more subs and views than mere thousands! Btw a little fun fact: you didn't say "Joule Thomson Effect" in the whole video; anyways, it was interesting! Thanks again!

  • @markkennedy9767
    @markkennedy9767 Před měsícem

    7:12 If the boundary condition is that our wavefunction psi(x,y,z) = X(x)Y(y)Z(z) = 0 when x = 0 or a, y = 0 or a, z = 0 or a, why do we choose to take X(x) = 0 when x = 0 or a, Y(y) = 0 when y = 0 or a and Z(z) = 0 when z = 0 ot a as our boundary conditions for the three Ordinary differential equations? We don't have to take these to satisfy the above boundary condition for psi(x,y,z)? For example, to satisfy psi(x,y,z) = 0, couldn't we have X(x) = a/2 when x = 0 for the first ODE, since Y(y) or Z(z) could still be zero instead meaning psi is zero. Or does the fact that X, Y and Z are independent functions preclude this.

  • @Mae-tr3lc
    @Mae-tr3lc Před měsícem

    I can't thank you enough. You've been helping me in my review for my licensure exam. Your explainations are very clear.

  • @leonschweiger4676
    @leonschweiger4676 Před měsícem

    Thank you so much for this concise explanation.

  • @yelyzavetapulnova4305
    @yelyzavetapulnova4305 Před měsícem

    Perfect explanation❤

  • @jonathancruz5091
    @jonathancruz5091 Před měsícem

    As a biochemistry scientist, I’ve used this Debye-Huckel formula along side Henderson-Hasselbach equation to prove a certain mobile phase solution recipe was wrong in the lab I work at and how the pH range was not inline with the method stated.

  • @barriehemming1189
    @barriehemming1189 Před měsícem

    another fantastic video thanks

  • @barriehemming1189
    @barriehemming1189 Před měsícem

    thank you for amazing upload it is much appreciated.💯

  • @barriehemming1189
    @barriehemming1189 Před měsícem

    thank you for the upload you actually made this make sense in my head.

  • @boombap3454
    @boombap3454 Před měsícem

    Entropy is always positive, right?

  • @mariyappillaiv5262
    @mariyappillaiv5262 Před měsícem

    Rigid rotator derivation send link sir

  • @crocketthill6401
    @crocketthill6401 Před měsícem

    How exactly does changing the limits of integration equate to throwing away one of the bars on the low end side fo the integral? My intuition tells me that by moving the bound to zero, you would essentially add in a bar of e^-0. Thank you so much for this series!

  • @PHouseholder
    @PHouseholder Před měsícem

    Thank you so much. This was really helpful

  • @carlosi.319
    @carlosi.319 Před měsícem

    how can you explain macromolecules transitions? (lipids, proteins and dna)

  • @itsawonderfullife4802
    @itsawonderfullife4802 Před měsícem

    very insightful. thank you prof.

  • @scnyoganand9861
    @scnyoganand9861 Před měsícem

    I have a doubt

  • @aalzien722
    @aalzien722 Před měsícem

    i hate physical chemistry

  • @cameronrivera3521
    @cameronrivera3521 Před měsícem

    Med student here! I remember the Shroedinger equation but we spent more time solving hydrogen and other calculus for energy states than extrapolating key concepts like thus, bravo!

  • @udittiwari2233
    @udittiwari2233 Před měsícem

    Is Q here the molecular partition function or the canonical partition function?

  • @samh3239
    @samh3239 Před měsícem

    There’s is an inproper rotation S for the Q right. If you rotate 180 degrees through the axis pointing to you out of the screen (the dot in the middle of the Q being the tip of the arrow pointing towards you) the little line of the Q is in the top left part of the circkle inverting through the center brings it back to the right bottom. 4:27

  • @user-hp7os5oj5y
    @user-hp7os5oj5y Před měsícem

    I learned from other class that this equation can lead to Le Chatelier's principle about the change of T, but I still can't understand how.

    • @nathanbarnes3969
      @nathanbarnes3969 Před 7 dny

      Not sure if this answers your question but this equation basically says that the rate of change of free energy, with respect to temperature, is negative with respect to temperature squared, not sure how this can be converted to systems in equilibrium but so long as the system is closed, this negative proportional relationship means that changing the temperature favours the reaction that reverses the direction of temperature change

  • @megawobbaffet8029
    @megawobbaffet8029 Před měsícem

    cool

  • @rajnibala5963
    @rajnibala5963 Před 2 měsíci

    From India, helped a lot for school thank you ❤❤

    • @diligentmist23
      @diligentmist23 Před měsícem

      life of jee Students like us! btw which class r u in?

  • @lonefairy4233
    @lonefairy4233 Před 2 měsíci

    Thank you sir !

  • @RichardKCollins
    @RichardKCollins Před 2 měsíci

    I would pre-heat the oxygen and fuel molecules electromagnetically. Then record the 3D volumetric temperature distribution, tracking flow of reactants. To start. And find the temperature dependent heat capacities data or models. To start. Calibrate and optimized the linked models. Track spectroscopic IR, VIS, thermal, UV, whatever is available. Share the results. Richard Collins, The Internet Foundation

  • @joesmith3550
    @joesmith3550 Před 2 měsíci

    Thanks for these videos. Although it is extremely unlikely that you are generating much ad revenue from my views, these videos are making a huge impact on my educational success. I'm reviewing my textbook for next semester; it might as well be Egyptian hieroglyphics without your help.

  • @legendaryx2k19
    @legendaryx2k19 Před 2 měsíci

    holy sh+t that was the best explaination of exact differentiation application. Explaination + & - was very helpful